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Sorption kinetic studies using metal chelate embedded polymers for recovery of heavy metals from desalination effluents

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TLDR
In this article, a post-irradiation induced graft polymerization technique was used for the recovery of heavy metals such as uranium and vanadium from desalination effluents.
Abstract
The heavy metals, such as uranium and vanadium, are some of the valuable metals in desalination effluents. Metal Chelate Embedded Polymers (MCEP) in leaflet form were prepared using the post-irradiation induced graft polymerisation technique, with different non-woven thermally bonded fibrous substrate materials. The novel sorbents, synthesised by using accelerator energy beams of 1.25 MeV and 2 MeV, were characterised for their radiation, chemical and mechanical characteristics. The novel sorbent was evaluated under different parametric conditions, in order to study the influence of grafting levels, initial concentration, dissolved solids and contact time. The standard isotherm and diffusion models were fitted to the experimental sorption data and model parameters were evaluated. The sorption characteristics of MCEP for recovery of heavy metals such as uranium and vanadium from desalination effluents were investigated.

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Journal ArticleDOI

Macroporous monoliths for trace metal extraction from seawater

TL;DR: In this paper, macroporous monolith adsorbents were prepared from the copolymerization of acrylonitrile and N,N′-methylene-bis(acrylamide) based on a cryogel method using both hydrophobic and hydrophilic monomers.
Journal ArticleDOI

Technology to Harvest Uranium from Seawater and Its Estimation by Laser Fluorimetry

TL;DR: In this article, the radiochemical separation procedure standardised for determining the concentrations of uranium metal ions from lean solutions of seawater/brine and its estimation by laser fluorimetry (LF) was presented.
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