Journal ArticleDOI
Spectra and some reactions of organopolysilanes
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This article is published in Journal of Organometallic Chemistry.The article was published on 1980-11-04. It has received 118 citations till now.read more
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The polysilane high polymers
TL;DR: In this article, the authors discuss reactions des polymeres de polysilane, photochimie et scission, reticulation des polysilanes, applications technologiques des poly(diorganosilylenes)
Journal ArticleDOI
Synthesis and Electronic Properties of 9,10-Disilylanthracenes
TL;DR: The sila-functional 9,10 disilylanthracenes An(SiR2X)2 (1, R = i-Pr, X = H; 2, R=i-Pr and X = Cl; 3, R|Me|, X| = H| and R| = Me, X | = H) were synthesized and the X-ray structure was reported for 1.9 at room temperature as discussed by the authors.
Journal ArticleDOI
Comparison between SiMe2 and CMe2 spacers as sigma-bridge for photoinduced charge transfer
C.A. van Walree,M.R. Roest,Wouter Schuddeboom,Leonardus W. Jenneskens,Jan W. Verhoeven,John M. Warman,Huub Kooijman,Anthony L. Spek +7 more
TL;DR: The potential of dimethylsilylene and isopropylidene U-spacers as bridges for photoinduced charge transfer (CT) in 4-cyano-4'-dimethylamino)- and 4-cyclo-methoxy-substituted diphenyldimethylsilanes and 2,2-diphen- ylpropanes was studied in this article.
Journal ArticleDOI
Alkynes between main group elements: from dumbbells via rods to squares and tubes
Rolf Gleiter,Daniel B. Werz +1 more
TL;DR: The CtC triple bond proved to be reactive toward electrophiles, nucleophiles, hydrogenation reagents, various catalysts, light, and heat makes it an ideal reagent for the formation of new C-C bonds and of high interest in industry and research laboratories.
Journal ArticleDOI
Emission Spectra of σ-π-Conjugated Organosilicon Copolymers Consisting of Alternating Dimethylsilylene and Aromatic Units
TL;DR: In this article, a series of σ−π conjugated organosilicon copolymers, −[(SiMe2)mA]n− (m = 1, 2, 3, 4, and 6), with alternating dimethylsilylene and π-conjugated units (A = phenylene, diphenylene, and anthranylene) in various solvents were performed.
References
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Journal ArticleDOI
Theory and Applications of Ultraviolet Spectroscopy
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Chemistry of organosilicon compounds
TL;DR: In this paper, two 1,2-disilacyclobutenes were prepared by the reaction of tetramethyldisilene with acetylenes, and several reactions of these new 1 2 disilacy clobutenets including oxidation, silylene insertion, iron carbonyl insertion, and addition to acetylene and dienes are reported.
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Experimental and Theoretical Study of Sigma‐Bond Electronic Transitions in Alkanes
TL;DR: In this paper, a qualitative interpretation of the observed spectra has been developed using independent-systems theory in connection with a simple model in which excitations in only C-C bonds are considered.