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Spin-Forbidden Transitions in the Spectra of Transition Metal Ions and Nephelauxetic Effect

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This article is published in ECS Journal of Solid State Science and Technology.The article was published on 2016-01-01. It has received 186 citations till now. The article focuses on the topics: Nephelauxetic effect & Spin (physics).

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Mn2+ and Mn4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review

TL;DR: An overview of recent studies on transition metal activated phosphors can be found in this article, including detailed synthesis routes (solid-state reaction and wet-chemical synthesis) and description of luminescence mechanisms and phosphors' behaviors; discuss their promising applications in white light-emitting diodes.
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Non-Rare-Earth BaMgAl10–2xO17:xMn4+,xMg2+: A Narrow-Band Red Phosphor for Use as a High-Power Warm w-LED

TL;DR: In this paper, a red-emitting phosphor BaMgAl10−2xO17:xMn4+,xMg2+ is successfully synthesized, which exhibits bright and narrow-band luminescence peaking at 660 nm with a full width at half-maximum of merely ∼30 nm upon blue light excitation.
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Research progress and application prospects of transition metal Mn4+-activated luminescent materials

TL;DR: In this paper, transition metal Mn4+-doped materials showing very narrow red emission have attracted tremendous interest for compositions based on abundant resources and mild production processes, resulting in a highly efficient way to obtain phosphors with favorable luminescence properties.
Journal ArticleDOI

Ratiometric Optical Thermometer Based on Dual Near-Infrared Emission in Cr3+-Doped Bismuth-Based Gallate Host

TL;DR: In this paper, a detailed spectroscopic analysis of the electronic configuration of Cr3+ in Bi2Ga4O9 is presented, which exhibits unique luminescent properties arising from the crystal field experienced by Cr3+, with simultaneous strong sharp and broadband near-infrared emissions from the 2E and 4T2 excited states, in a wide range of temperature.
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Photoluminescence properties of Mn4+-activated oxide phosphors for use in white-LED applications: A review

TL;DR: In this paper, the photoluminescence properties of Mn4+-activated oxide phosphors are reviewed, including Germinates, silicates, aluminates, perovskites, double perovsites, and so on.
References
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Journal ArticleDOI

Stimulated Optical Radiation in Ruby

TL;DR: Schawlow and Townes as discussed by the authors proposed a technique for the generation of very monochromatic radiation in the infra-red optical region of the spectrum using an alkali vapour as the active medium.
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The Theory of the Transition‐Metal Ions

J. S. Griffith, +1 more
- 01 Oct 1962 - 
Book

The Theory of Transition-Metal Ions

TL;DR: In this paper, the strong-filed coupling scheme was proposed to overcome the weak-field coupling scheme in paramagnetic resonance, which was shown to be effective in the case of free atoms and ions.
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On the Absorption Spectra of Complex Ions II

TL;DR: In this paper, the authors solved the energy levels which are important in the absorption spectra of the normal complex ions, leaving the crystalline field strength as a parameter The values of B and C (Racah's parameters) there needed are determined from the observed spectras of free ions or in some cases by extrapolation The f -values of the transitions which connect energy levels calculated are estimated and compared with the observed intensities.
Book

Optical spectroscopy of inorganic solids

TL;DR: In this article, the authors present symmetry and group representation theory for Inorganic Solids and Spectroscopy of Lanthanide (rare-earth) and Actinide Ions in Solids.
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