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Stereochemically Nonrigid Structures
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This article is published in Accounts of Chemical Research.The article was published on 1970-08-01. It has received 151 citations till now. The article focuses on the topics: Thesaurus (information retrieval).read more
Citations
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Coordination chemistry and catalysis with hemilabile oxygen-phosphorus ligands
Armin Bader,Ekkehard Lindner +1 more
TL;DR: In this article, the authors classify O,P ligands: ether-phosphines and furylphosphine, β-ketophosphines, δ-ketophosphine and β-carboxylates, αphosphinosulphoxides and their complexes.
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Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation.
TL;DR: Structural characterization of a high spin iron(0) alkyne and a bis(silane) sigma-complex has been accomplished and in combination with isotopic labeling studies provides insight into the mechanism of both catalytic C-H and catalyticC-Si bond formation.
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The adsorption of CO on Pt(111) studied by infrared reflection—Absortion spectroscopy
TL;DR: In this article, the interaction between CO and a clean Pt(111) surface at adsorption temperatures between 85 and 300 K has been studied with infrared reflection-absorption spectroscpy (IRAS) as well as with TPD and LEED.
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A chemiosmotic molecular mechanism for proton‐translocating adenosine triphosphatases
TL;DR: A simple chemiosmotic molecular mechanism for the reversible proton-translocating ATPases is suggested, which has several characteristics by which it may be recognised experimentally, and may therefore help to stimulate further research on this subject.
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Transition-metal polyhydride complexes
TL;DR: A recent review of polyhydride complexes can be found in this paper, where a number of properties of polyhedral polyhydrides have been discussed, such as their relative stability to loss of H2, and their ability to tolerate thermal, photochemical or protolytic H2 loss.
References
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Correlation of Rates of Intramolecular Tunneling Processes, with Application to Some Group V Compounds
TL;DR: In this paper, the WKB expression for tunneling frequencies permits correlation of these frequencies for members of homologous series of molecules, and the necessary data required are the tunneling rate for one member of the series, and structural parameters and vibrational frequencies for all members of interest.
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The symmetry groups of non-rigid molecules
TL;DR: In this article, the concept of molecular symmetry is extended to molecules such as ethane and hydrazine, which can pass from one conformation to another, and examples are given to illustrate the use of this concept in determining the statistical weights of individual levels and selection rules for electric dipole transitions between them.
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Nuclear Magnetic Resonance Multiplets in Liquids
TL;DR: In this paper, the number and relative intensities of the components of a multiplet were determined by the number of and statistical weights of the various nuclear spin orientations of the nuclei causing the splitting.