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Substrate effect on the optical response of silver nanoparticles

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TLDR
In this article, the influence of a substrate on the surface plasmon resonance absorption in silver nanoparticles depending on the distance between the nanoparticles and the substrate was studied. But the influence was negligible when the clusters were at a distance d>2R from the substrate.
Abstract
We study the influence of a substrate on the surface plasmon resonance absorption in silver nanoparticles depending on the distance between the nanoparticles and the substrate. The experimentally observed red shift of the resonant absorption is explained in the frame of the image-induced charges at the interface between the ambient medium and the substrate. The influence of a metallic substrate is negligible when the clusters are at a distance d>2R from the substrate. A dielectric substrate has much less influence on the optical response of silver clusters than a metallic one.

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Citations
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Journal ArticleDOI

Calculated Absorption and Scattering Properties of Gold Nanoparticles of Different Size, Shape, and Composition: Applications in Biological Imaging and Biomedicine

TL;DR: While nanorods with a higher aspect ratio along with a smaller effective radius are the best photoabsorbing nanoparticles, the highest scattering contrast for imaging applications is obtained from nanorod of high aspect ratio with a larger effective radius.
Journal ArticleDOI

Controlling the synthesis and assembly of silver nanostructures for plasmonic applications

TL;DR: In plasmonics, the metal nanostructures can serve as antennas to convert light into localized electric fields (E-fields) or as waveguides to route light to desired locations with nanometer precision through a strong interaction between incident light and free electrons in the nanostructure.
Journal ArticleDOI

Localized surface plasmon resonance spectroscopy of single silver nanocubes

TL;DR: In this work, dark-field microscopy is used to observe a new plasmon resonance effect for a single silver nanocube in which the plAsmon line shape has two distinct peaks when the particles are located on a glass substrate.
Journal ArticleDOI

Properties and Applications of Colloidal Nonspherical Noble Metal Nanoparticles

TL;DR: This Review highlights morphology-dependent properties of nonspherical noble metal nanoparticles with a focus on localized surface plasmon resonance and local field enhancement, as well as their applications in various fields including Raman spectroscopy, fluorescence enhancement, analytics and sensing, photothermal therapy, (bio-)diagnostics, and imaging.
Journal ArticleDOI

Plasmonic nanostructures: artificial molecules.

TL;DR: An entire family of plasmonic nanostructures, artificial molecules, has been developed whose optical properties can be understood within this picture: nanoparticles, multi-nanoparticle assemblies, and a nanoparticle-over-metallic film, an electromagnetic analog of the spinless Anderson model.
References
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Book

Classical Electrodynamics

Journal ArticleDOI

Optical Constants of the Noble Metals

TL;DR: In this paper, the optical constants for the noble metals (copper, silver, and gold) from reflection and transmission measurements on vacuum-evaporated thin films at room temperature, in the spectral range 0.5-6.5 eV.
Book

Absorption and Scattering of Light by Small Particles

TL;DR: In this paper, a Potpourri of Particles is used to describe surface modes in small Particles and the Angular Dependence of Scattering is shown to be a function of the size of the particles.
Journal ArticleDOI

Surface plasmon subwavelength optics

TL;DR: By altering the structure of a metal's surface, the properties of surface plasmons—in particular their interaction with light—can be tailored, which could lead to miniaturized photonic circuits with length scales that are much smaller than those currently achieved.