Journal ArticleDOI
Synthesis and characterization of ruthenium diiminodiphosphine complexes. X-ray structure of trans-Ru(P2N2)Cl2 · 2H2O (P2N2 = N,N′-bis [o-(diphenylphosphino)benzylidene]ethylenediamine)
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TLDR
The interaction of Ru(OAc)2(Ph3P)2 with 1 equivalent of N,N′-bis[o-(diphenylphosphino)benzylidene]ethylenediamine (P2N2) in refluxing dichloromethane gives trans-Ru(O Ac)2Cl2·2H2O (III) in good yield as mentioned in this paper.About:
This article is published in Polyhedron.The article was published on 1993-06-01. It has received 19 citations till now. The article focuses on the topics: Ethylenediamine & Ruthenium.read more
Citations
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Five- and Six-Coordinate Ruthenium(II) Complexes Containing 2-Ph2PC6H4CHNtBu and 2-Ph2PC6H4CH2NHtBu as Chelate Ligands: Synthesis, Characterization, and Catalytic Activity in Transfer Hydrogenation of Ketones
TL;DR: In this article, the crystal structures of five-and six-coordinate ruthenium(II) complexes containing imino-and aminophosphines have been determined by X-ray diffraction.
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Synthesis and characterization of iron(2+) and ruthenium(2+) diimino-, diamino- and diamido-diphosphine complexes. X-ray crystal structure of trans-RuCl2(P2N2C2H4) ∗d CHCl3
TL;DR: In this paper, the interaction of RuCl2(DMSO)4 with one equivalent of N,N′-bis[o-(diphenylphosphino)benzylidene]-1,6-diaminohexane (P2N2C6) in refluxing gave trans-FeCl 2(P2C2H4) (VIII).
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Ruthenium complexes with chiral tetradentate PNNP ligands: Asymmetric catalysis from the viewpoint of inorganic chemistry
TL;DR: This is a personal account of the application of ruthenium complexes containing chiral tetradentate ligand set (PNNP) as catalyst precursors for enantioselective "atom transfer" reactions, which involve bond formation between a metal-coordinated molecule and a free reagent.
Journal ArticleDOI
Novel ruthenium(II) complexes containing imino- or aminophosphine ligands for catalytic transfer hydrogenation
TL;DR: In this paper, five-and six-coordinate ruthenium(II) complexes containing imino-and aminophosphines have been prepared by ligand exchange processes.
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Asymmetric transfer hydrogenation of prochiral ketones catalyzed by chiral ruthenium complexes with aminophosphine ligands
Jing-Xing Gao,Pian-Pian Xu,Xiaodong Yi,Chuan-bo Yang,Hui Zhang,Shou-heng Cheng,Huilin Wan,Khi-Rui Tsai,Takao Ikariya +8 more
TL;DR: In this paper, the condensation of (S )-propane-1,2-diamine with two equivalents of o -diphenylphosphino)benzaldehyde gives ( S )-N, N, N ′-bis[ o -(diphosphino)-benzylidene]propane]-1, 2-Diamine [( S ]- 1 ] ligand The reduction of ( S)- 1 with excess NaBH 4 is carried out in refluxing ethanol to afford corresponding (S)-
References
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BINAP: an efficient chiral element for asymmetric catalysis
Ryoji Noyori,Hidemasa Takaya +1 more
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Centenary Lecture. Chemical multiplication of chirality: science and applications
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Metal complexes of diiminodiphosphines. Structural and reactivity patterns
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Synthesis and characterization of ruthenium acetate complexes containing triphosphines
TL;DR: A series of ruthenium(II) acetate complexes were synthesized and characterized by 31 P{ 1 H}, 1 H, and 13 C{ 1H} NMR and IR spectroscopy as mentioned in this paper.