Journal ArticleDOI
Synthesis, crystal structure and luminescent properties of one coordination polymer of cadmium(II) with mixed thiocyanate and hexamethylenetetramine ligands
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TLDR
The luminescent properties of the title complex in the solid state were investigated and a novel Cd(II) coordination polymer with hexagonal metallocyclic rings was synthesized and characterized.About:
This article is published in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.The article was published on 2009-03-01. It has received 42 citations till now. The article focuses on the topics: Coordination polymer & Thiocyanate.read more
Citations
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Single Crystal of New Nanostructure Self-Assembled Copper–Cyanide and Hexamethylenetetramine as an Efficient Supramolecular Coordination Polymer Catalyst
TL;DR: In this article, the X-ray structure of the supramolecular coordination polymer (SCP) [Cu6(CN)7(C6H12N4)2(OH3)], 1 was obtained by the reaction of K3[Cu(CN),4] and hexamethylenetetetramine (hmt) in presence of Me3SnCl at ambient conditions.
Journal ArticleDOI
Hydrothermal Synthesis, Crystal Structure and Luminescent Properties of a Three Dimensional Polyoxometalate-Based Supramolecular Structure: [CuI(phen)2]4[HPW11.5 VICu0.5 IIO40]
TL;DR: A polyoxometalate-based polyoxide-based complex has been synthesized by hydrothermal method and characterized by IR, elemental analysis, TG technique and X-ray crystallography as mentioned in this paper.
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Two d10-metal-organic frameworks based on polydentate Schiff-base ligand derived from biphenyl dihydrazide: Synthesis, crystal structure and luminescent properties
TL;DR: In this paper, two d 10 -metal-organic frameworks were synthesized and characterized by IR, elemental analyses, XRPD, TG technique and complete X-ray single crystal structure analyses, where the solvent molecules were filled into the macrometallacyclic ring units through multiform hydrogen bonds.
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Synthesis, Crystal Structure and Luminescent Properties of One Silver Complex with 3,5-Diphenylpyrazole
TL;DR: In this paper, a new Ag(I) complex Ag(HL)2(NO3) 1 has been synthesized with 3,5-diphenylpyrazole (HL) and characterized by IR spectrum, elemental analysis and X-ray crystallography.
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Synthesis, Crystal Structure, and Luminescent Properties of Two Ternary Complexes with Mixed Thiocyanate and Quinoline Ligands
TL;DR: In this article, two ternary complexes from SCN− and quinoline were synthesized and characterized by IR, UV, elemental analysis and X-ray crystallography, and the luminescent properties of the complexes 1−2 at room temperature were investigated.
References
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Journal ArticleDOI
Engineering coordination polymers towards applications
TL;DR: In this paper, the development in the field of coordination polymers or metal-organic coordination networks, MOCNs (metal-organic frameworks, MOFs) is assessed in terms of property investigations in the areas of catalysis, chirality, conductivity, luminescence, magnetism, spin-transition (spin-crossover), nonlinear optics (NLO) and porosity or zeolitic behavior upon which potential applications could be based.
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Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates.
TL;DR: This metal-organic polymer exhibits strong photoluminescence at room temperature, and the main emission band is at about 430 nm (lambda(ex) = 325 nm).
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Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures.
Jing-Cao Dai,Xintao Wu,Zhi-Yong Fu,Chuan-Peng Cui,Shengmin Hu,Wen-Xin Du,Li-Ming Wu,Han-Hui Zhang,Rui-Qing Sun +8 more
TL;DR: Three novel complexes of cadmium(II)-trimesate coordination polymers are obtained from hydrothermal reaction, in which the T-shaped molecular bilayer motif and chicken-wire-like motif are further interlinked in interdigitating or alternating fashion to construct the different coordination architectures.
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A new inorganic-organic photoluminescent material constructed with helical Zn-3(mu(3)-OH)(mu(2)-OH) chains
TL;DR: A photoluminescent inorganic−organic material formulated as [Zn3(μ3-OH)(μ2- OH)(4,4‘-bpy)0.5(4, 4’-oba)2]·0.
Journal ArticleDOI
Hydrothermal Syntheses, Crystal Structures, and Characteristics of a Series of Cd-btx Coordination Polymers (btx = 1,4-Bis(triazol-1-ylmethyl)benzene)
TL;DR: Polymers 2-4 display strong fluorescent emissions in the solid state at room temperature and the effects of temperature on the hydrothermal reaction system of btx and CdSO(4) and found that different products can be obtained at different temperatures.