Journal ArticleDOI
Synthesis, crystal structure and luminescent properties of one coordination polymer of cadmium(II) with mixed thiocyanate and hexamethylenetetramine ligands
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TLDR
The luminescent properties of the title complex in the solid state were investigated and a novel Cd(II) coordination polymer with hexagonal metallocyclic rings was synthesized and characterized.About:
This article is published in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.The article was published on 2009-03-01. It has received 42 citations till now. The article focuses on the topics: Coordination polymer & Thiocyanate.read more
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A one-dimensional polyoxometalate-based polymer [Cu(DMF)6][PMoVMoVI11O40Cu(DMF)4]·DMF: Crystal structure and luminescent properties
TL;DR: The polyoxometalate-based 1D coordination polymer 1 was synthesized and characterized by IR, UV spectroscopy and single-crystal X-ray diffraction analysis and the luminescent properties of 1 in the solution and in the solid state were investigated.
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Synthetic, spectral, structural and catalytic activity of infinite 3-D and 2-D copper(ii) coordination polymers for substrate size-dependent catalysis for CO2 conversion.
Bhaskaran,Manoj Trivedi,Anita Yadav,Gurmeet Singh,Abhinav Kumar,Girijesh Kumar,Ahmad Husain,Nigam P. Rath +7 more
TL;DR: The high efficiency and size-dependent selectivity toward small epoxides on catalytic CO2 cycloaddition make 1 a promising heterogeneous catalyst for carbon fixation and it can be used as a recoverable stableheterogeneous catalyst without any loss of performance.
Journal ArticleDOI
The structure and thermal behaviour of sodium and potassium multinuclear compounds with hexamethylenetetramine
TL;DR: In this article, the authors described the coordination polyhedra of the central atoms as distorted tetragonal bipyramids, and showed that the three dimensional hybrid network in which the classical two-dimensional coordination polymers are linked by inorganic SCN− spacers to the third dimension can be formed.
Journal ArticleDOI
Two 2D Cd(II) coordination polymers based on asymmetrical Schiff-base ligand: Synthesis, crystal structures and luminescent properties
TL;DR: Two new two-dimensional coordination polymers [Cd(3)L(2)(SCN)(6)](n) (1) and[CdLI(2) (2) have been synthesized and characterized by IR spectroscopy, elemental analysis, TG technique, XRPD and complete single crystal structure analysis.
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Two Cd(II) coordination polymers based on asymmetrical Schiff-base ligand with five- and six-membered N-containing heterocyclic rings: Synthesis, crystal structures and luminescent properties
TL;DR: Two cadmium inorganic-organic hybrid coordination polymers [CdL(SCN)2]n (1) and [CdLI 2]n(2), have been synthesized and characterized by IR spectroscopy, elemental analysis, XRPD, thermogravimetric (TG) analyses and X-ray crystallography, where L is 4-(pyridine-4-yl)methyleneamino-1,2,4-triazole.
References
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Journal ArticleDOI
Engineering coordination polymers towards applications
TL;DR: In this paper, the development in the field of coordination polymers or metal-organic coordination networks, MOCNs (metal-organic frameworks, MOFs) is assessed in terms of property investigations in the areas of catalysis, chirality, conductivity, luminescence, magnetism, spin-transition (spin-crossover), nonlinear optics (NLO) and porosity or zeolitic behavior upon which potential applications could be based.
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Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates.
TL;DR: This metal-organic polymer exhibits strong photoluminescence at room temperature, and the main emission band is at about 430 nm (lambda(ex) = 325 nm).
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Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures.
Jing-Cao Dai,Xintao Wu,Zhi-Yong Fu,Chuan-Peng Cui,Shengmin Hu,Wen-Xin Du,Li-Ming Wu,Han-Hui Zhang,Rui-Qing Sun +8 more
TL;DR: Three novel complexes of cadmium(II)-trimesate coordination polymers are obtained from hydrothermal reaction, in which the T-shaped molecular bilayer motif and chicken-wire-like motif are further interlinked in interdigitating or alternating fashion to construct the different coordination architectures.
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A new inorganic-organic photoluminescent material constructed with helical Zn-3(mu(3)-OH)(mu(2)-OH) chains
TL;DR: A photoluminescent inorganic−organic material formulated as [Zn3(μ3-OH)(μ2- OH)(4,4‘-bpy)0.5(4, 4’-oba)2]·0.
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Hydrothermal Syntheses, Crystal Structures, and Characteristics of a Series of Cd-btx Coordination Polymers (btx = 1,4-Bis(triazol-1-ylmethyl)benzene)
TL;DR: Polymers 2-4 display strong fluorescent emissions in the solid state at room temperature and the effects of temperature on the hydrothermal reaction system of btx and CdSO(4) and found that different products can be obtained at different temperatures.