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Showing papers in "Synthetic Metals in 2012"


Journal ArticleDOI
TL;DR: In this article, the progress of poly(3,4-ethylenedioxythiophene) (PEDOT)-based thermoelectric (TE) materials having been made in recent years is presented.

253 citations


Journal ArticleDOI
TL;DR: The study confirmed that polyaniline has not induced any sensitization and skin irritation either and cytotoxicity, which was higher for polyAniline hydrochloride compared to polyanILine base and was observed on both cell lines, was caused rather by the reaction by-products and residues than by polyanile itself.

237 citations


Journal ArticleDOI
TL;DR: In this article, a batch-sorption system using eco-friendly polymer/bio-polymer composite (polyaniline/chitosan) as an adsorbent was investigated to remove sulfonated dyes from aqueous solution.

183 citations


Journal ArticleDOI
TL;DR: In this article, the thermoelectric properties of polyaniline/graphene nanosheets (PANI/GNs) bulk composite pellets and films have been prepared with PANI to GNs weight ratios ranging from 4:1 to 1:1.

146 citations


Journal ArticleDOI
TL;DR: LiFePO4 is a potential green cathode material for lithium-ion power batteries in the 21st century for its high theoretical capacity, stable voltage plateau of 3.5 V vs. Li/Li+, good stability both at room temperature and high temperature, excellent cycling performance, high safety, low raw material cost, no pollution, and rich source of raw materials as mentioned in this paper.

133 citations


Journal ArticleDOI
TL;DR: In this article, a PAN-lignin copolymer with acrylonitrile (AN) was used for the production of low-cost carbon fibers, which showed the presence of the C N group of PAN co-eluting with ether, hydroxyl, and aromatic groups that are attributed to lignin.

133 citations


Journal ArticleDOI
TL;DR: In this paper, a facile chemical oxidation polymerization approach was used to synthesize PPy/ZnO composites with varying amounts of zinc oxide (0.20 -20 kg) via facile chemolymmetric polymerization and XRD, FT-IR, TGA, DSC, SEM and four-probe method respectively.

118 citations


Journal ArticleDOI
TL;DR: In this paper, the fabrication of polyaniline (PANI)/carbon nanotube (CNT) nanohybrids using a novel approach of CNT-templated polymerization process was reported.

77 citations


Journal ArticleDOI
TL;DR: In this paper, a magnetic multi-walled carbon nanotubes/ferrite (NiFe2O4) nanocomposite was prepared by physical mixing and X-ray diffraction and Fourier transform infrared spectroscopy confirm the preparation of the ferrite nanoparticles.

76 citations


Journal ArticleDOI
TL;DR: In this article, a one-step synthesis of Ni/graphene nanocomposites via a substrate-free, atmospheric-pressure chemical vapor deposition process is presented. But the synthesis process is not described.

75 citations


Journal ArticleDOI
TL;DR: In this article, a fuzzy network of polyaniline thin film is successfully synthesized for ammonia gas detection application using Fourier transform infrared spectroscopy, field emission scanning electron microscope (FESEM), transmission electron microscope and optical absorption studies.

Journal ArticleDOI
Young Soo Yun1, Do-Hyeong Kim1, Bona Kim1, Hyun Ho Park1, Hyoung-Joon Jin1 
TL;DR: In this article, a transparent conducting film (TCF) with high flexibility was successfully prepared by using graphene oxide (GO) and silver nanowire (Ag NW) hybrids.

Journal ArticleDOI
TL;DR: In this paper, the opto-electrical and photovoltaic properties of polyazomethines with fluorene moieties in the main chain were presented and the polymer solar cells devices were fabricated by spin coating the blend solution of the three polymers as donor and PCBM as acceptor.

Journal ArticleDOI
TL;DR: In this article, a simple and inexpensive successive ionic layer adsorption and reaction (SILAR) method was used to obtain polythiophene thin films at room temperature.

Journal ArticleDOI
TL;DR: In this article, the relationship between surface morphology of poly ortho aminophenol (POAP) films and synthesis conditions was investigated, and it was found that the morphology of POAP varies with the synthesis conditions of the pulse.

Journal ArticleDOI
TL;DR: The phase composition of the composite materials was analyzed by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) as discussed by the authors, and the thermoelectric properties of composite powders, after cold pressing into pellets, were measured at temperatures between 293 and 423 K.

Journal ArticleDOI
TL;DR: In this paper, the conductivity and solubility of polypyrrole (PPy)/graphene composites has been successfully synthesized by in situ chemical oxidation polymerization using various concentrations of cationic polyelectrolyte poly(styrenesulfonate) (PSS) and ammonium peroxodisulfate (APS).

Journal ArticleDOI
TL;DR: The first charge transfer complexes of tetrathiafulvalene (1) with 1,2,5-chalcogenadiazole derivatives, i.e. with [1, 2,5]thiadiazolo[3, 4-c][1,2.5] thiadiaole (2) and 3,4-dicyano-1.2, 5-telluradiazoles (3), were designed, prepared in the form of air and thermally stable single crystals and structurally defined by X-ray diff

Journal ArticleDOI
TL;DR: Cell experiments with PC12 cells demonstrate that this scaffold is cytocompatible and the electrical stimulation of these microstructures promotes neurite outgrowth and orientation.

Journal ArticleDOI
TL;DR: In this article, a high-conversion synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) by chemical oxidative polymerization was studied.

Journal ArticleDOI
TL;DR: In this paper, a camphor sulfonic acid (CSA)-doped polypyrrole-zinc oxide (PPy-ZnO) hybrid sensor was used for detecting NO2 at room temperature.

Journal ArticleDOI
TL;DR: In this paper, polypyrrole (Ppy) nanoparticles were synthesized by surfactant-directed chemical oxidation method and confirmed by Fourier transform infrared spectroscopy and transmission electron microscopy.

Journal ArticleDOI
TL;DR: In this article, the authors characterized the properties of a transparent oxygen barrier film in which graphene oxide (GO) was used as the barrier material, and the deposited film displayed excellent oxygen barrier properties, decreasing the oxygen transmittance rate (OTR) to 0.05 cc/m 2 ǫ day.

Journal ArticleDOI
TL;DR: In this article, hollow poly(aniline-co-pyrrole) with significant electromagnetic properties were successfully prepared via the oxidative polymerization of a mixture of aniline and pyrrole in the presence of a magnetic fluid, using a non-ionic surfactant as a template.

Journal ArticleDOI
Kai Zhang1, Ling Wang1, Yanliang Liang1, Siqi Yang1, Jing Liang1, Fangyi Cheng1, Jun Chen1 
TL;DR: In this paper, the design and synthesis of a novel hole transporting materials (HTMs) with a central unit of adamantine and peripheral groups of triarylamine moieties was reported.

Journal ArticleDOI
TL;DR: In this paper, the phase composition of the composite materials was analyzed by X-ray diffraction and Fourier transform infrared spectra, and the thermoelectric properties of the cold pressed composite pellets with different GNs loadings were measured at room temperature.

Journal ArticleDOI
TL;DR: In this paper, the β-diketone ligand, 1-(4-methoxyphenyl)-3-phenylpropane-1,3-dione (MPPD), and its binary Eu(III) complexes Eu-MPPD) 3, ternary complexes eu(MPPD)-3 ·Bipy with 2,2-dipyridine (BipY) and Eu-(MPPD-3 ·Phen with 1,10-phenanthroline (Phen) were prepared.

Journal ArticleDOI
TL;DR: In this paper, poly(2-aminothiazole) derivatives were synthesized by chemical oxidative polymerization method using 2-AT, 2-ABT and 6-ethoxy-2aminobenzothiazoles (EtO -2ABT) as the monomers.

Journal ArticleDOI
Yong Kong1, Caiyun Wang1, Yang Yang1, Chee O. Too1, Gordon G. Wallace1 
TL;DR: In this article, a bioelectric battery that uses polypyrrole doped with a biological polyelectrolyte (dextran sulfate, an anti-coagulant) as the cathode and bioresorbable Mg alloy (AZ61) as anode was developed.

Journal ArticleDOI
TL;DR: In this article, the structural, morphological and electro-magnetic properties of the nanocomposites were performed by Fourier transform infrared (FT-IR), X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM), four-probe conductivity tester and vibrating sample magnetometer (VSM).