Journal ArticleDOI
Synthesis, crystal structure, magnetic behavior and thermal property of three polynuclear complexes : [M(dca)2(H2O)2]n · (hmt)n [M = Mn(II), Co(II)] and [Co(dca)2(bpds)]n [dca, dicyanamide; hmt, hexamethylenetetramine; bpds, 4,4'-bipyridyl disulfide]
Subal Chandra Manna,Ananta Kumar Ghosh,Joan Ribas,Michael G. B. Drew,Chun-Nan Lin,Ennio Zangrando,Nirmalendu Ray Chaudhuri +6 more
Reads0
Chats0
TLDR
In this paper, three μ1,5-dicyanamide bridged Mn(II) and Co(II)-complexes have been synthesized and characterized by single crystal X-ray diffraction study, low temperature (300-2,K) magnetic measurement and thermal behavior.About:
This article is published in Inorganica Chimica Acta.The article was published on 2006-03-20. It has received 44 citations till now. The article focuses on the topics: Dicyanamide.read more
Citations
More filters
Journal ArticleDOI
Hexamethylenetetramine: An old new building block for design of coordination polymers
TL;DR: In this paper, the main structural and topological types of coordination polymers bearing hexamethylenetetramine (hmt) are summarized, showing that a diversity of metal-organic networks can be generated by facile self-assembly routes in aqueous medium and using rather simple chemicals.
Journal ArticleDOI
Co(II) Coordination Polymers: Positional Isomeric Effect, Structural and Magnetic Diversification
TL;DR: In this article, the influence of the positional isomeric ligands on the structures and magnetic properties of their complexes was systematically investigated, and it was shown that the phenyl dicarboxylate anions display versatile coordination modes to manage the Co(II) ions to f...
Journal ArticleDOI
Bimetal-organic framework-derived nanotube@cellulose aerogels for peroxymonosulfate (PMS) activation.
TL;DR: In this paper , a composite aerogel (CoFe0.8@NCNT@CA) loaded with bimetallic MOF-derived carbon nanotubes was developed for activating peroxymonosulfate (PMS) to degrade tetracycline (TC).
Journal ArticleDOI
First Dicyanamide-Bridged Spin-Crossover Coordination Polymer: Synthesis, Structural, Magnetic, and Spectroscopic Studies
Caroline Genre,Erwann Jeanneau,Azzedine Bousseksou,Dominique Luneau,Serguei A. Borshch,Galina S. Matouzenko +5 more
TL;DR: Analysis of the two-step spin-crossover character in this compound suggests that covalent interactions through the spacer ligand do not provide the main mechanism of cooperativity.
Journal ArticleDOI
New multidimensional coordination polymers with μ2-and μ3-dcno cyano carbanion ligand {dcno-= [ (NC )2CC (O)O (CH2)2OH]- }
Samia Benmansour,Samia Benmansour,Fatima Setifi,Smail Triki,Jean-Yves Salaün,Fanny Vandevelde,Jean Sala-Pala,Carlos J. Gómez-García,Thierry Roisnel +8 more
TL;DR: In this paper, a new polymeric materials [M(dcno)2(H2O)2] [M = FeII (1), CoII (2), MnII (4) with dcno− =[(NC)2CC(O)O(CH2)2OH]− = 2,2-dicyano-1-(2-hydroxyethoxy)ethenolate anion have been synthesised and characterised by IR spectroscopy, X-ray crystallography and magnetic measurements.
References
More filters
Journal ArticleDOI
Self‐Penetration—A Structural Compromise between Single Networks and Interpenetration: Magnetic Properties and Crystal Structures of [Mn(dca)2(H2O)] and [M(dca)(tcm)], M=Co, Ni, Cu, dca=Dicyanamide, N(CN)2−, tcm=Tricyanomethanide, C(CN)3−
TL;DR: Hysteresis measurements of coercive field and remnant magnetisation show that 1, 2 and 3 are soft magnets, 1 being a canted-spin antiferromagnet (weak ferromagnets), while 2 and3 are ferromagnets that display some unusual features in their high-field magnetisation isotherms in comparison to their related alpha-[M(dca)2] phases.
Journal ArticleDOI
1-D and 2-D homoleptic dicyanamide structures, [Ph4P]2[CoII[N(CN)2]4] and [Ph4P][M[N(CN)2]3] (M = Mn, Co).
James W. Raebiger,Jamie L. Manson,Roger D. Sommer,Urs Geiser,and Arnold L. Rheingold,Joel S. Miller +5 more
TL;DR: The homoleptic complexes [Ph(4)P](2)[Co[N(CN)(2)](4)] and [M](3)] [M = Co, Mn] have been structurally as well as magnetically characterized and long-range magnetic ordering was not observed in any of these materials.
Journal ArticleDOI
Syntheses, crystal structures and magnetic properties of copper(II) dicyanamide complexes; dinuclear, chain and ladder compounds
TL;DR: In this article, the preparation, crystal structures and magnetic properties of three heteroleptic copper(II) complexes with dicyanamide (dca) bridges, [Cu(bpca)(H2O)(dca)]2 (1) (bpca = bis(2-pyridylcarbonyl)amidate), [Cu[bpy)(dCA)2]n (2) (bpy = 2,2′-bipyridine),
Journal ArticleDOI
Copper(I) dicyanamide coordination polymers: ladders, sheets, layers, diamond-like networks and unusual interpenetration
TL;DR: The structures of six new derivatives of copper dicyanamide have been determined as mentioned in this paper, which are composed of 2D layers which each interpenetrate with four others in a parallel fashion, resulting in a novel 3D interlocking of layers.
Journal ArticleDOI
Structures and Magnetic Properties of Novel 1-D Coordination Polymers Containing Both Dicyanamide and Pyridine-Type Ligands
Jamie L. Manson,Atta M. Arif,Christopher D. Incarvito,Louise M. Liable-Sands,Arnold L. Rheingold,Joel S. Miller +5 more
TL;DR: In this article, three 1-D coordination polymers consisting of {l_brace}Mn[N(CN){sub 2}]{sub 2}{r_brace}{sub {infinity}} structural units and L = 2 pyridines (i.e., 2), 2,2{prime}-bipyridine (i., 3), and 4,4{prime]-bibyridine(i., 4) were synthesized and characterized by single crystal X-ray crystallography and magnetic susceptibility studies.