Journal ArticleDOI
Synthesis of Orthorhombic Mo‐V‐Sb Oxide Species by Assembly of Pentagonal Mo6O21 Polyoxometalate Building Blocks
Masahiro Sadakane,Masahiro Sadakane,Keiko Yamagata,Katsunori Kodato,Keisuke Endo,Koshiro Toriumi,Yoshiki Ozawa,Tomoji Ozeki,Takuro Nagai,Yoshio Matsui,Norihito Sakaguchi,William D. Pyrz,Douglas J. Buttrey,Douglas A. Blom,Thomas Vogt,Wataru Ueda +15 more
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TLDR
The first single-crystal X-ray analysis of an orthorhombic Mo-V-based oxide, a promising catalyst for light alkane selective oxidation known as the "M1 phase", revealed the structure of the compound.Abstract:
Mix and match: The pentagonal [Mo(6)O(21)](n-) polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo-V-Sb oxide. The first single-crystal X-ray analysis of an orthorhombic Mo-V-based oxide, a promising catalyst for light alkane selective oxidation known as the "M1 phase", revealed the structure of the compound.read more
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Polyoxometalates: Building Blocks for Functional Nanoscale Systems
TL;DR: The possibilities of creating highly sophisticated functional hierarchical systems with multiple, interdependent, functionalities along with a critical analysis that allows the non-specialist to learn the salient features of POMs are discussed.
Journal ArticleDOI
Polyoxometallate als Bausteine für funktionelle Nanosysteme
TL;DR: In this article, a periodensystem der Polyoxometallat-Baueinheiten (POM) is presented, in which a number of aktuelle Herausforderungen beim design funktioneller Systeme auf der Basis of POM-Baubien are discussed.
Journal ArticleDOI
From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry
Achim Müller,Pierre Gouzerh +1 more
TL;DR: The present review presents the first comprehensive report of current knowledge (including synthesis aspects not discussed before) regarding the related giant metal-oxide clusters mainly of the type {Mo(57)M'(6)} (M' = Fe(III), V(IV)) (torus structure),
Journal ArticleDOI
An orthorhombic Mo3VOx catalyst most active for oxidative dehydrogenation of ethane among related complex metal oxides
Takeshi Konya,Tomokazu Katou,Toru Murayama,Satoshi Ishikawa,Masahiro Sadakane,Douglas J. Buttrey,Wataru Ueda +6 more
TL;DR: In this article, four distinct structural types (orthorhombic, trigonal, tetragonal and amorphous) of Mo3VOx were synthesized by a hydrothermal method as a single phase, characterized structurally and tested for oxidative dehydrogenation of ethane.
Journal ArticleDOI
Porous Capsules {(M)M5}12FeIII30 (M=MoVI, WVI): Sphere Surface Supramolecular Chemistry with 20 Ammonium Ions, Related Solution Properties, and Tuning of Magnetic Exchange Interactions
Ana Maria Todea,Alice Merca,Hartmut Bögge,Thorsten Glaser,Joseph M. Pigga,Melissa L. K. Langston,Tianbo Liu,Ruslan Prozorov,Marshall Luban,Christian Schröder,William H. Casey,Achim Müller +11 more
References
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Journal ArticleDOI
A short history of SHELX
TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
Book ChapterDOI
Processing of X-ray diffraction data collected in oscillation mode
Zbyszek Otwinowski,Wladek Minor +1 more
TL;DR: The methods presented in the chapter have been applied to solve a large variety of problems, from inorganic molecules with 5 A unit cell to rotavirus of 700 A diameters crystallized in 700 × 1000 × 1400 A cell.
Journal ArticleDOI
WinGX suite for small-molecule single-crystal crystallography
TL;DR: The category Computer Program Abstracts provides a rapid means of communicating up-to-date information concerning both new programs or systems and signi®cant updates to existing ones.
Journal ArticleDOI
Single-crystal structure validation with the program PLATON
TL;DR: The results of a single-crystal structure determination when in CIF format can now be validated routinely by automatic procedures, and the concepts of validation and the classes of checks carried out by the program PLATON as part of the IUCr checkCIF facility are described.