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Synthesis, structures, and redox properties of some new dithiocarbamates that include a heteroaromatic ring

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TLDR
The potentials of polarographic oxidation on a rotating platinum electrode were determined for them and for previously synthesized N-substituted unsymmetrical dithiocarbamates of the same metals as discussed by the authors.
Abstract
New Cu, Ni, Pb, Zn, Co. Fe, Mn, Sb, and Bi dithiocarbamates that include 2-thenyl and 2-furfuryl radicals were synthesized. The potentials of polarographic oxidation on a rotating platinum electrode were determined for them and for the previously synthesized N-substituted unsymmetrical dithiocarbamates of the same metals. The results of x-ray diffraction analysis of bis-(di-2-thenyldithiocarbamato)nickel(2+) are presented and discussed.

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Ni(II), Pd(II) and Pt(II) complexes of N,N-bis(3,3-dimethyl-allyl)-dithiocarbamate: Synthesis, spectroscopic characterization, antimicrobial and molecular docking studies

TL;DR: In this paper , a potassium salt of N,N-bis(3,3-dimethyl-allyl)-dithiocarbamate has been synthesized from three step processes involving the synthesis of bis(3-3dimethyl)-allyl-cyanamide.
Journal ArticleDOI

Ni(II), Pd(II) and Pt(II) complexes of N,N-bis(3,3-dimethyl-allyl)-dithiocarbamate: Synthesis, spectroscopic characterization, antimicrobial and molecular docking studies

TL;DR: In this article, a potassium salt of N,N-bis(3,3-dimethyl-allyl)-dithiocarbamate has been synthesized from three step processes involving the synthesis of bis(3.3,dimethyl)-allyl-cyanamide and subsequent conversion to N, N-bis (3, 3,3dimethylallyl)amine, and its characterization of the ligand and its metal complexes were carried out using various spectroscopic and magnetic susceptibility measurements.
Journal ArticleDOI

New Building Blocks for Self-Healing Polymers

TL;DR: In this paper , a new series of tetrafuranic isocyanate-related ureas were used for the development of polyurethanes-like self-healing materials via the Diels-Alder reaction.
References
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Journal ArticleDOI

Über α‐Halogenäther, IV. Synthesen aromatischer Aldehyde mit Dichlormethyl‐alkyläthern

TL;DR: Aromatische Kohlenwasserstoffe geben with Dichlormethyl-alkylathern bei Gegenwart von Friedel-Crafts-Katalysatoren in guten Ausbeuten die entsprechenden Aldehyde Zur Darstellung der Chlorather im Labormasstab wird ein einfaches Verfahren angegeben as discussed by the authors.
Journal ArticleDOI

Microwave Spectra of Thiophene, 2‐ and 3‐Monodeutero, 3,3′‐Dideutero, and Tetradeuterothiophene. Structure of the Thiophene Molecule

TL;DR: In this article, the microwave spectra of ordinary thiophene (C4H4S) and the microwave spectrum of Tetradeuterothiophene were used to identify the rotational constants of all the 8 geometrical parameters of TTH.
Journal ArticleDOI

Metal ion and ligand dependency of the redox behaviour of some first row transition metal dithiocarbamates

TL;DR: For all the complexes examined, the relative ordering of the redox potentials with the dithiocarbamate substituents is remarkably consistent for both oxidation and reduction processes as mentioned in this paper.
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