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Journal ArticleDOI

Temperature-responsive shrinking kinetics of poly (N-isopropylacrylamide) copolymer gels with hydrophilic and hydrophobic comonomers

TLDR
In this paper, the authors investigated the shrinking kinetics of copolymer gels with the hydrophilic comonomer, acrylamide, and hydrophobic comonomers, butyl methacrylate, and found that the shrinking process is dominated by polymer network diffusion.
About
This article is published in Journal of Membrane Science.The article was published on 1995-05-15. It has received 146 citations till now. The article focuses on the topics: Poly(N-isopropylacrylamide) & Comonomer.

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Citations
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Journal ArticleDOI

Stimuli responsive polymers for biomedical applications

TL;DR: This critical review of polymers that can respond to external stimuli considers the types of stimulus response used in therapeutic applications and the main classes of responsive materials developed to date.
Journal ArticleDOI

Magnetic hydrogel nanocomposites for remote controlled pulsatile drug release

TL;DR: Remote controlled pulsatile drug release was characterized for different drugs as well as for different ON-OFF durations of the AMF.
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Rapid Deswelling Response of Poly(N-isopropylacrylamide) Hydrogels by the Formation of Water Release Channels Using Poly(ethylene oxide) Graft Chains

TL;DR: In this paper, the deswelling response on raising the temperature of this gel above the gel phase transition temperature (TP) takes place within 10 min, whereas a conventionally cross-linked PIPAAm gel of the same dimensions requires 1 month.
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Studies on anion exchange membranes having permselectivity for specific anions in electrodialysis — effect of hydrophilicity of anion exchange membranes on permselectivity of anions

TL;DR: Permselectivity of specific anions through the anion exchange membranes is governed mainly by the balance of hydration energy of anions with hydrophilicity of the membranes, partially by hydrated ionic size of the anions, except the membranes having an oppositely charged layer on the membrane surface.
Journal ArticleDOI

Tunable swelling kinetics in core--shell hydrogel nanoparticles.

TL;DR: The results suggest that the core--shell architecture is a powerful one for the design of colloidal "smart gels" with tunable properties and the formation of a thin, stable skin layer at the particle exterior during the early stages of particle collapse is the rate limiting factor in particle deswelling.
References
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Book

The mathematics of diffusion

John Crank
TL;DR: Though it incorporates much new material, this new edition preserves the general character of the book in providing a collection of solutions of the equations of diffusion and describing how these solutions may be obtained.
Journal ArticleDOI

Solution Properties of Poly(N-isopropylacrylamide)

TL;DR: In this paper, a lower critical solution temperature of poly(N-isopropyl acrylamide was found to be due to an entropy effect, which was attributed to the formation of nonpolar and intermolecular hydrogen bonds.
Journal ArticleDOI

Applications of thermally reversible polymers and hydrogels in therapeutics and diagnostics

TL;DR: Polymers and hydrogels have been synthesized which phase separate from aqueous solutions when the temperature is raised through a critical temperature region (LCST).
Journal ArticleDOI

Thermally on-off switching polymers for drug permeation and release

TL;DR: In this article, the swelling of crosslinked poly(N,N-alkyl substituted acrylamides) in water was studied in relation to changes in external temperature, and significant swelling changes of the polymer in water in response to temperature can be attributed to the delicate hydrophilic/hydrophobic balance of polymer chain, and was affected by the size, configuration and mobility of the alkyl side chains on the substituted acylamides.
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