Book ChapterDOI
The Transition Metal Coordination Chemistry of Hemilabile Ligands
Caroline S. Slone,Dana A. Weinberger,Chad A. Mirkin +2 more
- pp 233-350
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The article was published on 2007-03-09. It has received 223 citations till now. The article focuses on the topics: Coordination complex.read more
Citations
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Journal ArticleDOI
Smart N-Heterocyclic Carbene Ligands in Catalysis
TL;DR: This review is to comprehensively describe all types of smart NHC ligands by focusing attention on the catalytically relevant ligand-based reactivity.
Journal ArticleDOI
Cooperative catalysis with first-row late transition metals
TL;DR: A comprehensive overview of the current state-of-the-art in first-row transition metal cooperative catalysts can be found in this article. But the focus of this paper is on the metal-ligand bifunctional substrate activation.
Journal ArticleDOI
Symmetrical and unsymmetrical pincer complexes with group 10 metals: synthesis via aryl C-H activation and some catalytic applications.
TL;DR: The obtained symmetrical and unsymmetrical pincer complexes have been used as catalysts in Suzuki-Miyaura reaction (Pd), asymmetric Friedel-Crafts alkylation of indole with trans-β-nitrostyrene (Pt) as well as in asymmetric allylation of aldehyde and sulfonimine (P d).
Journal ArticleDOI
A highly active bifunctional iridium complex with an alcohol/alkoxide-tethered N-heterocyclic carbene for alkylation of amines with alcohols.
Agnieszka Bartoszewicz,Rocío Marcos,Suman Sahoo,A. Ken Inge,Xiaodong Zou,Belén Martín-Matute +5 more
TL;DR: A series of new iridium(III) complexes containing bidentate N-heterocyclic carbenes (N HC) functionalized with an alcohol or ether group (NHC-OR, R = H, Me) catalyzed the alkylation of anilines with alcohols as latent electrophiles to obtain insights into the mechanism and into the structure of possible catalytic intermediates.
Journal ArticleDOI
Use of Hemilabile N,N Ligands in Nitrogen-Directed Iridium-Catalyzed Borylations of Arenes
Abel Ros,Beatriz Estepa,Rocío López-Rodríguez,Eleuterio Álvarez,Rosario Fernández,José M. Lassaletta +5 more
TL;DR: This paper aims to demonstrate the efforts towards in-situ applicability of EMMARM, as to provide real-time information about concrete mechanical properties such as E-modulus and compressive strength in the response of the immune system to foreign substances.
References
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Journal ArticleDOI
The cysteine switch: a principle of regulation of metalloproteinase activity with potential applicability to the entire matrix metalloproteinase gene family.
H E Van Wart,H Birkedal-Hansen +1 more
TL;DR: Observations support the view that the cysteine-switch mechanism is applicable to all members of this gene family and offers the opportunity for multiple modes of physiological activation of these important enzymes.
Journal ArticleDOI
Coordination chemistry and catalysis with hemilabile oxygen-phosphorus ligands
Armin Bader,Ekkehard Lindner +1 more
TL;DR: In this article, the authors classify O,P ligands: ether-phosphines and furylphosphine, β-ketophosphines, δ-ketophosphine and β-carboxylates, αphosphinosulphoxides and their complexes.
Journal ArticleDOI
Preparation of a macrocyclic polynuclear complex, [(en)Pd(4,4'-bpy)]4(NO3)8 (en = ethylenediamine, bpy = bipyridine), which recognizes an organic molecule in aqueous media
Journal ArticleDOI
Asymmetric hydrogenation. Rhodium chiral bisphosphine catalyst
Billy D. Vineyard,William S. Knowles,Milton Jerome Sabacky,Gerald L. Bachman,D. J. Weinkauff +4 more
Journal ArticleDOI
Multiple modes of activation of latent human fibroblast collagenase: evidence for the role of a Cys73 active-site zinc complex in latency and a "cysteine switch" mechanism for activation.
TL;DR: In this article, the Cys73 residue is removed from the active-site zinc atom and its replacement by water, with the concomitant exposure of the active site to dithionitrobenzoate.
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