Journal ArticleDOI
Thermal, pressure and light switchable spin-crossover materials
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TLDR
The different approaches currently being explored in order to achieve multifunctionality in SCO materials are discussed.Abstract:
This article reviews the most relevant chemical and structural aspects that influence the spin-crossover phenomenon (SCO). Special attention is focussed on the recent development of SCO coordination polymers. The different approaches currently being explored in order to achieve multifunctionality in SCO materials are discussed.read more
Citations
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Journal ArticleDOI
Molecular spin crossover phenomenon: recent achievements and prospects
TL;DR: This critical review discusses recent work in the field of molecule-based spin crossover materials with a special focus on these emerging issues, including chemical synthesis, physical properties and theoretical aspects as well (223 references).
Journal ArticleDOI
Old materials with new tricks: multifunctional open-framework materials.
TL;DR: This critical review provides an up-to-date survey to this new generation of multifunctional open-framework solids, classified into five different sections: magnetic, chiral, conducting, optical, and labile open-frameworks for sensing applications.
Journal ArticleDOI
Control of magnetic properties through external stimuli.
TL;DR: Most of the Review is devoted to the properties of valence-tautomeric compounds, molecular magnets, and spin-crossover complexes, which could find future application in memory devices or optical switches.
Journal ArticleDOI
Structure:function relationships in molecular spin-crossover complexes
TL;DR: This critical review presents a survey of molecular spin-crossover compounds with good availability of crystallographic data and indicates that changes in molecular shape between the high- and low-spin states can play an important role in determining the existence and the cooperativity of a thermal spin-transition in the solid state.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Engineering coordination polymers towards applications
TL;DR: In this paper, the development in the field of coordination polymers or metal-organic coordination networks, MOCNs (metal-organic frameworks, MOFs) is assessed in terms of property investigations in the areas of catalysis, chirality, conductivity, luminescence, magnetism, spin-transition (spin-crossover), nonlinear optics (NLO) and porosity or zeolitic behavior upon which potential applications could be based.
Journal ArticleDOI
Crystal engineering of NLO materials based on metal-organic coordination networks
Owen R. Evans,Wenbin Lin +1 more
TL;DR: In this article, the authors present the development of crystal-engineering strategies toward the synthesis of non-centrosymmetric infinite coordination networks for use as second-order nonlinear optical (NLO) materials.
Journal ArticleDOI
Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-Bipyridine
Journal ArticleDOI
Selective binding and removal of guests in a microporous metal–organic framework
TL;DR: In this paper, a metal-organic framework was designed to bind aromatic guest molecules selectively, and the inclusions can be selectively readsorbed, even after the removal of included guest molecules, and they showed that the crystal lattice was thermally stable up to 350 °C.
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