Journal ArticleDOI
Thermal stability of organopalladium compounds: Non-radical methyl elimination from [PdXMe(PEt3)2]
Antonino Morvillo,A. Turco +1 more
TLDR
Deuterium isotopic labeling shows that the rate increase is accompanied by a change from an intramolecular to a radical mechanism involving the abstraction of hydrogen by the methyl groups as discussed by the authors.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1984-11-27. It has received 4 citations till now. The article focuses on the topics: Methyl group & Organopalladium.read more
Citations
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Book ChapterDOI
Palladium–Carbon σ-Bonded Complexes
C.J. Elsevier,M.R. Eberhard +1 more
TL;DR: In this article, the chemistry of organopalladium sigma-bonded complexes has been discussed, including aryl, allyl, and alkylpaladium(ii) complexes as well as dinuclear and Pd cluster complexes.
References
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Journal ArticleDOI
Preparation and reactions of triethylphosphine complexes of zerovalent nickel, palladium, and platinum
Journal ArticleDOI
Reaction of coordinated phosphines. VI. Divalent palladium promoted cleavage of carbon-phosphorus bonds in tertiary phosphines
Kiyoshi Kikukawa,Tsutomu Matsuda +1 more
TL;DR: In this paper, the role of divalent palladium in the cleavage of carbon-phosphorus bond of tertiary phosphines is revealed by the study of the phenylation in the Pd(OAc) 2 Ph 3 P-styrene system under various conditions; reaction atmosphere, ratio of Ph 3 p/Pd p/pd p 2, and addition of ethanol or Cu II (OAc 2 · H 2 O.
Journal ArticleDOI
Funktionelle Trimethylphosphinderivate, VII: Ambivalentes Verhalten von Tetrakis(trimethylphosphin) eisen: Zum Verlauf der Reaktion mit CH3I
TL;DR: In this paper, a tetrakis(trimethylphosphine) iodide complex is formed by attack on the FeC bond, probably by an attack on a hydridoiron ionide complex.
Journal ArticleDOI
Reactions of methyl and ethyl halides with the complexes Ni[P(C2H5)3]4 and Ni(X)[P(C2H5)3]3
Antonino Morvillo,A. Turco +1 more
TL;DR: The first step of the reaction of nickel(0) with CH3I is the expected oxidative addition of the halide to the metal substrate, and the intermediate thus formed decomposes to produce ethane (and small amounts of methane) without further reaction with the organic halide as discussed by the authors.
Journal ArticleDOI
Bond energies and thermal decomposition of [Pt(X)(CH3)(P(C2H5)3)2] complexes
TL;DR: In this paper, the first-order rate constant of trideuteriomethyl complexes was found to be independent on the nature of the ligand X and the temperature used.