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Journal ArticleDOI

Total synthesis of O-methylpallidinine

John E. McMurry, +1 more
- 01 Jan 1983 - 
- Vol. 24, Iss: 43, pp 4653-4656
TLDR
In this article, a 16-step synthesis of methylpallidinine from 1,4-cyclohexanedione and 3-bromoveratrole was described.
About
This article is published in Tetrahedron Letters.The article was published on 1983-01-01. It has received 31 citations till now. The article focuses on the topics: Morphinan & Total synthesis.

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Citations
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Journal ArticleDOI

Palladium-Catalyzed Amination of Aryl Triflates

TL;DR: Elect electronically neutral aryl triflates gave higher yields of arylamines than did electron deficient aryL trifLates, presumably due to the increased rate of base-promoted triflate cleavage in electron deficient substrates.
Journal ArticleDOI

Enantioselective total synthesis of erogorgiaene: applications of asymmetric Cu-catalyzed conjugate additions of alkylzincs to acyclic enones.

TL;DR: The first enantioselective synthesis of erogorgiaene, an inhibitor of mycobacterium tuberculosis, is disclosed and some of the special properties of nonphosphine Ru complex 3 as a highly effective catalyst for olefin cross-metathesis are showcased.
Journal ArticleDOI

Total synthesis of the Kopsia lapidilecta alkaloid (+/-)-lapidilectine B.

TL;DR: This constitutes the first synthesis of a member of the 5,6,12,13-tetrahydro-11a,13a-ethano-3H-pyrrolo[1‘,2‘:1,8]azocino[5,4-b]indole class of alkaloids.
References
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Journal ArticleDOI

Studies directed towards the total synthesis of morphine alkaloids

TL;DR: In this paper, a formal total synthesis of (±)-morphine has been completed and the application of metallated enamines to the synthesis of morphine related congeners is reported.
Journal ArticleDOI

A practical synthesis of codeine from dihydrothebainone

TL;DR: 1,5beta, 7alpha-Tribromodihydrothebainone has been identified as the main product in the tribromination of dihydrothe bainone, and Hydrolysis to codeinone and borohydride reduction give codeine in 70% overall yield.
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