Journal ArticleDOI
Transition Metal−Boryl Compounds: Synthesis, Reactivity, and Structure
Geoffrey J. Irvine,M. J. Gerald Lesley,Todd B. Marder,Nicholas C. Norman,Craig R. Rice,Edward G. Robins,Warren R. Roper,George R. Whittell,L. James Wright +8 more
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This article is published in Chemical Reviews.The article was published on 1998-12-17. It has received 504 citations till now. The article focuses on the topics: Reactivity (chemistry).read more
Citations
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C−H Activation for the Construction of C−B Bonds
TL;DR: Investigations revealed that the conversion of C-H bonds to C-B bonds was both thermodynamically and kinetically favorable and highlighted the accessible barriers for C- H bond cleavage and B-C bond formation during the borylation of alkanes and arenes.
Journal ArticleDOI
The nature of the bonding in transition-metal compounds.
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Thermal, Catalytic, Regiospecific Functionalization of Alkanes
TL;DR: The rhodium complex Cp*Rh(eta(4)-C(6)Me(6)) (Cp*, C(5)Me (5); Me, methyl) catalyzes the high-yield formation of linear alkylboranes from commercially available borane reagents under thermal conditions.
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Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse
TL;DR: Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored and these compounds now feature prominently in both metal-catalyzed and metal-free methodologies for the formation of B-C bonds and other processes.
References
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Journal ArticleDOI
Structure and chemistry of bis(cyclopentadienyl)-MLn complexes
Joseph W. Lauher,Roald Hoffmann +1 more
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Platinum(0)-catalyzed diboration of alkynes
TL;DR: In this paper, the first syn-selective addition of tetraalkoxydiboron 1 to alkenes was reported, which was efficiently catalyzed by the platinum(0) complex.