Book ChapterDOI
Transition Metal Complexes Containing Bidentate Phosphine Ligands
W. Levason,C.A. Mcauliffe +1 more
TLDR
In this paper, several transition metal complexes containing bidentate phosphine ligands are described, and a major complication in diphosphine complexes is the relative complexity of the ligands.Abstract:
Publisher Summary This chapter describes several transition metal complexes containing bidentate phosphine ligands. The bonding in metal–phosphine ligands due to the formation of π-type bonds between the metal and phosphorus atoms. Several techniques are used to study metal–phosphine complexes. These techniques include mass spectroscopy infrared spectroscopy, nuclear magnetic resonance, electronic spectroscopy, electron spin resonance, and Mossbauer spectroscopy. A major complication in diphosphine complexes is the relative complexity of the ligands. When a diphosphine complexes with a metal ion, the electron density on the phosphorus atom changes, and the ligand is restricted in the conformation it can assume. Thus the vibrational spectra of the free and coordinated ligands differ.read more
Citations
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Journal ArticleDOI
Coordination chemistry of diphosphinoamine and cyclodiphosphazane ligands
Maravanji S. Balakrishna,V. Sreenivasa Reddy,Setharampattu S. Krishnamurthy,John F. Nixon,J.C.T.R.Burckett St. Laurent +4 more
TL;DR: The transition metal coordination and organometallic chemistry of acyclic diphosphazane ligands has grown rapidly in the last two decades and a stage has been reached that permits a delineation of similarities and contrasts with the chemistry of Diphosphinomethane type ligands.
Journal ArticleDOI
Gold-Komplexe von Diphosphinomethanen, I. Synthese und Kristallstruktur zweikerniger Gold(I)-Verbindungen
TL;DR: In this article, a 1:2-Komplexe with AuCl, Aul, and AuCH3 is described, and the results are of interest with respect to the short but nonbonding AuAu distance.
Journal ArticleDOI
An investigation of the chelate effect: The binding of bidentate phosphine and arsine chelates in square-planar transition metal complexes
Journal ArticleDOI
Beiträge zur Strukturchemie von Silberhalogenid-Diphosphinomethan- und verwandten Komplexen†
TL;DR: The 1:1-komplex of AgBr with bis(diphenylphosphino)methane (dppm) was first reported in this article, where the structure consists of discrete bromide anions and trinuclear cations.
References
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Journal ArticleDOI
Adducts of tungsten(V) halides
TL;DR: In this article, the adducts WCl5py2,WCl5 bipy, and WCl 5 diphos have been prepared by reaction of tungsten hexachloride with the appropriate ligand in benzene or carbon tetrachlorides solution.
Journal ArticleDOI
Complex formation by 1,2-bis(dimethylarsino)tetrafluorocyclobutene and its diphenylphosphino analog,
TL;DR: In this article, a survey of the chelating properties of substituted pentafluorocyclobutenes (R = (CH3)2As (ffars) or (C6H5)2P (ffos)) is described.
Journal ArticleDOI
Notiz zur Umsetzung von Rheniumpentacarbonylhalogeniden mit Tetraphenyldiphosphin, ‐diarsin und Kaliumdiphenylphosphid
Walter Hieber,Werner Opavsky +1 more
Journal ArticleDOI
Reactions of diphos and diars with iron carbonyls: a reinvestigation
W. R. Cullen,D. A. Harbourne +1 more
TL;DR: The bidentate ligands diars (1) and diphos (2) react with iron carbonyls to give the previously known diarsFe(CO)3, DiphosFe( CO)3 and DipsosFe2(CO), and the new complex diars Fe2CO)8 as mentioned in this paper.
Journal ArticleDOI
Some oxo-complexes of molybdenum(IV) and (V) with 1,2-bisdiphenylphosphinoethane
A. V. Butcher,J. Chatt +1 more
TL;DR: In this article, the structures of complexes formulated [{MoOCl3(diphos), MoOCl2, MoOOCl4, [MoOCL2]+], MoO(OR) with alcohols in the presence of sodium carbonate, and [MoCl2(thf) with tetrahydrofuran were given.
Related Papers (5)
Ditertiary Phosphine Complexes of Nickel. SpeCtral, Magnetic, and Proton Resonance Studies. A Planar-Tetrahedral Equilibrium
An investigation of the chelate effect: The binding of bidentate phosphine and arsine chelates in square-planar transition metal complexes
Phosphine, Arsine, and Stibine Complexes of the Transition Elements
C. A. McAuliffe,W. Levason +1 more