Journal ArticleDOI
Why do the luminescence maxima of isostructural palladium(II) and platinum(II) complexes shift in opposite directions
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TLDR
In this article, a series of palladium(II) and platinum (II) complexes with thiocyanate, halide, and dithiocarbamate ligands are presented.Abstract:
Temperature-dependent luminescence spectra for a series of palladium(II) and platinum(II) complexes with thiocyanate, halide, and dithiocarbamate ligands are presented. All complexes show broad d−d...read more
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Near-infrared 2Eg → 4A2g and visible LMCT luminescence from a molecular bis-(tris(carbene)borate) manganese(IV) complex
Joe P. Harris,Christian Reber,Hannah E. Colmer,Timothy A. Jackson,Adam P. Forshaw,Jeremy M. Smith,R. Adam Kinney,Joshua Telser +7 more
TL;DR: The molecular bis-(tris(carbene)borate) manganese (IV) complex [{PhB(MeIm)3}2Mn](OTf)2 shows 2Eg → 4A2g luminescence at 828 nm in the solid state at 85 K; this wavelength is longer by approximately...
Journal ArticleDOI
Dithiocarbamate complexes of platinum group metals: Structural aspects and applications
TL;DR: The incorporation of dithiocarbamate ligands in the preparation of metal complexes is largely prompted by the versatility of this molecule as mentioned in this paper, which can be obtained from the study of such metal complexes ranging from their preparation, the solid-state properties, solution behavior as well as their applications as bioactive materials and luminescent compounds.
Journal ArticleDOI
Interpreting effects of structure variations induced by temperature and pressure on luminescence spectra of platinum(II) bis(dithiocarbamate) compounds.
TL;DR: The crystal structures indicate that decreasing intermolecular interactions with increasing pressure are likely to contribute to the exceptionally high shift for Pt(MeDTC)2.
Journal ArticleDOI
Variation of M···H-C Interactions in Square-Planar Complexes of Nickel(II), Palladium(II), and Platinum(II) Probed by Luminescence Spectroscopy and X-ray Diffraction at Variable Pressure.
Stéphanie Poirier,Hudson Lynn,Christian Reber,Elodie Tailleur,Mathieu Marchivie,Philippe Guionneau,Michael R. Probert +6 more
TL;DR: High-resolution crystal structures and crystal structures at variable pressure for [Pt{(CH3)2DTC}2] indicate that intermolecular M···H-C interactions are at the origin of these different shifts.
Journal ArticleDOI
Pressure-induced variations of MLCT and ligand-centered luminescence spectra in square-planar platinum(II) complexes
Alexandre Rodrigue-Witchel,David L. Rochester,Shu Bin Zhao,Kevin B. Lavelle,J. A. Gareth Williams,Suning Wang,William B. Connick,Christian Reber +7 more
TL;DR: In this article, solid-state luminescence spectra of five crystalline platinum(II) complexes at variable pressure and temperature were compared, showing that the luminance spectra can be broad bands, characteristic of MLCT transitions, or vibronically structured, typical of intraligand transitions.
References
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Journal ArticleDOI
A short history of SHELX
TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
Journal ArticleDOI
OLEX2: a complete structure solution, refinement and analysis program
TL;DR: OLEX2 seamlessly links all aspects of the structure solution, refinement and publication process and presents them in a single workflow-driven package, with the ultimate goal of producing an application which will be useful to both chemists and crystallographers.
Journal ArticleDOI
WinGX suite for small-molecule single-crystal crystallography
TL;DR: The category Computer Program Abstracts provides a rapid means of communicating up-to-date information concerning both new programs or systems and signi®cant updates to existing ones.
Journal ArticleDOI
The semiclassical way to molecular spectroscopy
TL;DR: In this paper, a new perspective on the interaction of light with molecules is presented, which deals with a new viewpoint on the interactions between light and molecules and shows that light can be used as a probe of molecular structure and dynamics, and sometimes light acts as a reagent or product in a chemical reaction.
Journal ArticleDOI
IL MILIONE: a suite of computer programs for crystal structure solution of proteins
Maria Cristina Burla,Rocco Caliandro,Mercedes Camalli,Benedetta Carrozzini,Giovanni Luca Cascarano,Liberato De Caro,C. Giacovazzo,Giampiero Polidori,Dritan Siliqi,Riccardo Spagna +9 more
TL;DR: Is a suite of computer programs devoted to protein crystal structure determination by X-ray crystallography, which automatically uses the above information to phase protein reflections, and may succeed even with structures with up to 6000 non-H atoms in the asymmetric unit.
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