As the environment preservation gradually becomes a matter of major social concern and more strict legislation is being imposed on effluent discharge, more effective processes are required to deal with non-readily biodegradable and toxic pollutants. Synthetic organic dyes in industrial effluents cannot be destroyed in conventional wastewater treatment and consequently, an urgent challenge is the development of new environmentally benign technologies able to mineralize completely these non-biodegradable compounds. This review aims to increase the knowledge on the electrochemical methods used at lab and pilot plant scale to decontaminate synthetic and real effluents containing dyes, considering the period from 2009 to 2013, as an update of our previous review up to 2008. Fundamentals and main applications of electrochemical advanced oxidation processes and the other electrochemical approaches are described. Typical methods such as electrocoagulation, electrochemical reduction, electrochemical oxidation and indirect electro-oxidation with active chlorine species are discussed. Recent advances on electrocatalysis related to the nature of anode material to generate strong heterogeneous OH as mediated oxidant of dyes in electrochemical oxidation are extensively examined. The fast destruction of dyestuffs mediated with electrogenerated active chlorine is analyzed. Electro-Fenton and photo-assisted electrochemical methods like photoelectrocatalysis and photoelectro-Fenton, which destroy dyes by heterogeneous OH and/or homogeneous OH produced in the solution bulk, are described. Current advantages of the exposition of effluents to sunlight in the emerging photo-assisted procedures of solar photoelectrocatalysis and solar photoelectro-Fenton are detailed. The characteristics of novel combined methods involving photocatalysis, adsorption, nanofiltration, microwaves and ultrasounds among others and the use of microbial fuel cells are finally discussed.

Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods. An updated review

2.2. Fenton’s Chemistry 6575 2.2.1. Origins 6575 2.2.2. Fenton Process 6575 2.3. Photo-Fenton Process 6577 3. H2O2 Electrogeneration for Water Treatment 6577 3.1. Fundamentals 6578 3.2. Cathode Materials 6579 3.3. Divided Cells 6580 3.4. Undivided Cells 6583 4. Electro-Fenton (EF) Process 6585 4.1. Origins 6585 4.2. Fundamentals of EF for Water Remediation 6586 4.2.1. Cell Configuration 6586 4.2.2. Cathodic Fe2+ Regeneration 6586 4.2.3. Anodic Generation of Heterogeneous Hydroxyl Radical 6587

Electro-Fenton process and related electrochemical technologies based on Fenton's reaction chemistry

Adsorption of methylene blue on low-cost adsorbents: A review

The science of the total environment

Fouling in membrane bioreactors used in wastewater treatment

Study on the suitable thickness of a PAC-precoated dynamic membrane coupled with a bioreactor for municipal wastewater treatment

Influence of activated sludge properties on flux behavior in osmosis membrane bioreactor (OMBR)

A pilot scale up-flow anaerobic sludge blanket (UASB) coupled with cross-flow membrane filtration was used to treat low strength municipal wastewater in Singapore. The application of membrane filtration as a polishing unit of UASB effluent could produce better effluent quantity than conventional UASB. In this research, with gradually reducing hydraulic retention time from 10.0 to 5.5 h , membrane effluent was able to meet the more stringent effluent criterion over the whole experiment. Simultaneously, biogas yield increased from 61.8 to 120.7 mL∕g CODremoved , in which methane percentages were also increased from 59.3 to 65.2%, respectively. Furthermore, the results of anaerobic membrane filtration showed that there were three different methods could effectively mitigate rapid membrane fouling and maintain trans-membrane pressure as low and stable as possible. These would reduce membrane cleaning frequency and prolong membrane life span.

Fenglin Yang

Papers

Study on the suitable thickness of a PAC-precoated dynamic membrane coupled with a bioreactor for municipal wastewater treatment

Influence of activated sludge properties on flux behavior in osmosis membrane bioreactor (OMBR)

Municipal Wastewater Treatment Using a UASB Coupled with Cross-Flow Membrane Filtration

Stable photocatalytic activity of immobilized Fe0/TiO2/ACF on composite membrane in degradation of 2,4-dichlorophenol

Start-up of the anammox process and membrane fouling analysis in a novel rotating membrane bioreactor