H
Henri Rudler
Researcher at Pierre-and-Marie-Curie University
Publications - 174
Citations - 2082
Henri Rudler is an academic researcher from Pierre-and-Marie-Curie University. The author has contributed to research in topics: Carbene & Ketene. The author has an hindex of 25, co-authored 174 publications receiving 2061 citations. Previous affiliations of Henri Rudler include Cergy-Pontoise University & Centre national de la recherche scientifique.
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Journal ArticleDOI
Reaction of aminocarbene complexes of chromium with alkynes. 1. Formation and rearrangement of ketene and nitrogen ylide complexes
Evelyne Chelain,Régis Goumont,Louis Hamon,Andrée Parlier,M. Rudler,Henri Rudler,Jean Claude Daran,Jacqueline Vaissermann +7 more
TL;DR: The title reactions of chromium-containing carbene complexes (CO) 5 Cr=(R 1 )N(R 2 R 3 ) (R 1 =H, Me, Ph; R 2 =Me; R 3 =Me, C 3 H 5, CH 2 C 3H 5 ) 8 and (CO 5 Cr=C[(CH 2 ) 3 C≡CPh]N
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Assessment of MTO as a catalyst for the synthesis of acid sensitive epoxides. Use of the biphasic system H2O2/CH2Cl2 with and without bipyridine and influence of the substituents on the double bonds
TL;DR: In this paper, the selective epoxidation of alkenes in the biphasic medium CH2Cl2/H2O2/HO2H2HO 2 was studied.
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Bis(trimethylsilyl)ketene Acetals as C,O-Dinucleophiles: One-Pot Formation of Polycyclic γ- and δ-Lactones from Pyridines and Pyrazines
TL;DR: In this article, the regio-and diastereoselectivities of the addition reactions, together with the presence or absence of rotamers, have been established, and most of the new structures were assigned through X-ray crystal structure determinations.
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Bidentate alkene-aminocarbene complexes of chromium. Synthesis and reactivity toward alkynes
TL;DR: The reaction of the aminocarbene complex (CO) 5 Cr=C(CH 3 )NHCH 2 CH=CH 2 with lithium diisopropylamide followed by methyl iodide led, to (CO, 5 Cr =C( CH 3 )N( CH 2 CH =CH 2 and, to(CO, 4 Cr = C(CH 2 )N (CH 3 ),CH 2, CH = CH 2 )
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Reaction of aminocarbene complexes of chromium with alkynes. 2. Intramolecular insertions leading to polycyclic lactams
Evelyne Chelain,Andrée Parlier,Max Audouin,Henri Rudler,Jean Claude Daran,Jacqueline Vaissermann +5 more
TL;DR: In this article, the authors examined the thermolysis of chromium-containing carbene complexes of the general structure (CO) 5 Cr=C(NR 2 R 3 )-(CH 2 ) n C=C-R 1) and showed that the insertions of the triple bond and of CO, followed by a rearrangement to tricyclic lactams, are observed.