Carbon capture and storage (CCS) is broadly recognised as having the potential to play a key role in meeting climate change targets, delivering low carbon heat and power, decarbonising industry and, more recently, its ability to facilitate the net removal of CO2 from the atmosphere. However, despite this broad consensus and its technical maturity, CCS has not yet been deployed on a scale commensurate with the ambitions articulated a decade ago. Thus, in this paper we review the current state-of-the-art of CO2 capture, transport, utilisation and storage from a multi-scale perspective, moving from the global to molecular scales. In light of the COP21 commitments to limit warming to less than 2 °C, we extend the remit of this study to include the key negative emissions technologies (NETs) of bioenergy with CCS (BECCS), and direct air capture (DAC). Cognisant of the non-technical barriers to deploying CCS, we reflect on recent experience from the UK's CCS commercialisation programme and consider the commercial and political barriers to the large-scale deployment of CCS. In all areas, we focus on identifying and clearly articulating the key research challenges that could usefully be addressed in the coming decade.

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Carbon capture and storage (CCS): the way forward

Preface 1. Basic tools 2. Elasticity and Hooke's law 3. Seismic wave propagation 4. Effective media 5. Granular media 6. Fluid effects on wave propagation 7. Empirical relations 8. Flow and diffusion 9. Electrical properties Appendices.

/pdf/the-rock-physics-handbook-tools-for-seismic-analysis-of-58lw74s1oi.pdf

The Rock Physics Handbook: Tools for Seismic Analysis of Porous Media

Responding to the latest developments in rock physics research, this popular reference book has been thoroughly updated while retaining its comprehensive coverage of the fundamental theory, concepts, and laboratory results. It brings together the vast literature from the field to address the relationships between geophysical observations and the underlying physical properties of Earth materials - including water, hydrocarbons, gases, minerals, rocks, ice, magma and methane hydrates. This third edition includes expanded coverage of topics such as effective medium models, viscoelasticity, attenuation, anisotropy, electrical-elastic cross relations, and highlights applications in unconventional reservoirs. Appendices have been enhanced with new materials and properties, while worked examples (supplemented by online datasets and MATLAB® codes) enable readers to implement the workflows and models in practice. This significantly revised edition will continue to be the go-to reference for students and researchers interested in rock physics, near-surface geophysics, seismology, and professionals in the oil and gas industries.

The Rock Physics Handbook

Review of natural gas hydrates as an energy resource: Prospects and challenges ☆

A compilation of compressional-wave ( V p) and shear-wave ( V s) velocities and densities for a wide variety of common lithologies is used to define new nonlinear, multivalued, and quantitative relations between these properties for the Earth's crust. Wireline borehole logs, vertical seismic profiles, laboratory measurements, and seismic tomography models provide a diverse dataset for deriving empirical relations between crustal V p and V s. The proposed V s as a function of V p relations fit V s and V p borehole logs in Quaternary alluvium and Salinian granites as well as laboratory measurements over a 7-km/sec-wide range in V p. The relations derived here are very close to those used to develop a regional 3D velocity model for southern California, based on pre-1970 data, and thus provide support for that model. These data, and these relations, show a rapid increase in V s as V p increases to 3.5 km/sec leading to higher shear-wave velocities in young sedimentary deposits than commonly assumed. These relations, appropriate for active continental margins where earthquakes are prone to occur, suggests that amplification of strong ground motions by shallow geologic deposits may not be as large as predicted by some earlier models.

Empirical relations between elastic wavespeeds and density in the Earth's crust

Seismic reflections depend on the contrasts of the elastic properties of the subsurface and their 3D geometry. As a result, interpreting seismic data for petrophysical rock properties requires a theoretical rock-physics model that links the seismic response to a rock’s velocity and density. Such a model is based on controlled experiments in which the petrophysical and elastic rock properties are measured on the same samples, such as in the wellbore. Using data from three wells drilled through a clastic offshore gas reservoir, we establish a theoretical rock-physics model that quantitatively explains these data. The modeling is based on the assumption that only three minerals are present: quartz, clay, and feldspar. To have a single rock-physics transform to quantify the well data in the entire intervals under examination in all three wells, we introduced field-specific elastic moduli for the clay. We then used the model to correct the measured shear-wave velocity because it appeared to be unreason...

Rock-physics diagnostics of an offshore gas field

Characterization of geochemical properties and factors controlling the pore structure development of shale gas reservoirs

Critical-Porosity Models

Experimental results of laboratory measurements at ultrasonic frequencies on dry opaline rocks are documented from the Monterey Formation, a siliceous unit in the San Joaquin basin. In these samples the silica is primarily biogenic opal-A in origin, but progressively alters to opal-CT and then quartz with depth. The diagenetic transitions are accompanied by a marked porosity reduction. Compressional and shear wave velocities were measured on core plugs at effective reservoir pressure. Experimental results on samples from the opal-A/opal-CT transition and the opal-CT/quartz transition show very little pressure-dependence of elasticwave velocities. When their elastic moduli are normalized by those of the solid phase, the moduli-porosity trend is very close to that of chalk and, in the lower-porosity domain, of some clean sandstones.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/97GL01959

Ultrasonic velocities of opaline rocks undergoing silica diagenesis


 Published laboratory elastic-wave velocity versus porosity data in carbonate rocks exhibit significant scatter even at a fixed mineralogy. This scatter is usually attributed to the strong variability in the rock-frame or pore-space geometry, which, in turn, is driven by the richness and complexity of diagenetic alteration in these very reactive sediments. Yet, by examining wireline data from oil-bearing high-to-medium porosity chalk deposits, we find surprisingly tight velocity–porosity trends. Moreover, these trends are continued into the low-porosity domain by data from a location thousands of miles away from the chalk field. This congruence implies a universality of diagenetic trends, at least in the massive deposits under examination. We also find that the elastic bulk and shear moduli of the pure-calcite end member are somewhat smaller than such values reported in the literature. Using the end-member elastic constants relevant to the data under examination, we establish a theoretical rock physics model to match and generalize these data.

Jack Dvorkin

Papers

Rock-physics diagnostics of an offshore gas field

Characterization of geochemical properties and factors controlling the pore structure development of shale gas reservoirs

Critical-Porosity Models

Ultrasonic velocities of opaline rocks undergoing silica diagenesis

Velocity–porosity–mineralogy trends in chalk and consolidated carbonate rocks