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Showing papers by "Joydeep Dutta published in 2018"


Journal ArticleDOI
TL;DR: In this paper, a review of the most recent reported advancements in the field of hysteresis behavior during CO oxidation is presented, which sheds light on the origin of this phenomenon and the parameters that influence the type, shape, and width of the conversion of the hystresis curves.
Abstract: There is a growing demand for new heterogeneous catalysts for cost-effective catalysis. Currently, the hysteresis phenomenon during low-temperature CO oxidation is an important topic in heterogeneous catalysis. Hysteresis provides important information about fluctuating reaction conditions that affect the regeneration of active sites and indicate the restoration of catalyst activity. Understanding its dynamic behavior, such as hysteresis and self-sustained kinetic oscillations, during CO oxidation, is crucial for the development of cost-effective, stable and long-lasting catalysts. Hysteresis during CO oxidation has a direct influence on many industrial processes and its understanding can be beneficial to a broad range of applications, including long-life CO2 lasers, gas masks, catalytic converters, sensors, indoor air quality, etc. This review considers the most recent reported advancements in the field of hysteresis behavior during CO oxidation which shed light on the origin of this phenomenon and the parameters that influence the type, shape, and width of the conversion of the hysteresis curves.

70 citations


Journal ArticleDOI
TL;DR: It is shown that specific spectral signatures are present for the cause as well as the effect of staphylococcal osteomyelitis, opening the possibility of developing a useful diagnostic modality for early and rapid diagnosis of this condition.
Abstract: Diagnosis of osteomyelitis presents a formidable challenge. Lack of pathognomonic clinical sign(s) and diagnostic tests that can diagnose osteomyelitis at an early stage contribute to this difficulty. If the diagnosis is not made early, the disease becomes very difficult to eradicate and can lead to limb threatening and potentially life-threatening complications. Staphylococcus aureus is the most common organism causing osteomyelitis. Raman Spectroscopy provides information about molecular vibration that could potentially be harnessed as a spectral signature for cellular changes in specific pathologic conditions. In this study we describe a technique using Raman spectroscopy that could potentially be used to diagnose staphylococcal osteomyelitis. Human bone samples were co-cultured with Staphylococcus aureus (S. aureus) and the effects of bacterial growth on bone quality were then monitored using Raman spectroscopy. A major drop in the bone mineral quality and crystallinity was observed in the infected bones compared to the controls. S. aureus infection was also found to alter the collagen cross-linking. Our study shows that specific spectral signatures are present for the cause as well as the effect of staphylococcal osteomyelitis, opening the possibility of developing a useful diagnostic modality for early and rapid diagnosis of this condition.

68 citations


Journal ArticleDOI
TL;DR: It is demonstrated that the chitosan-ZnO nanocomposite coatings not only maintains the quality of the packed okra but also retards microbial and fungal growth.
Abstract: Efficiency of nanocomposite zinc oxide-chitosan antimicrobial polyethylene packaging films for the preservation of quality of vegetables was studied using okra Abelmoschus esculentus. Low density polyethylene films (LDPE) coated with chitosan-ZnO nanocomposites were used for packaging of okra samples stored at room temperature (25 °C). Compared to the control sample (no coating), the total bacterial concentrations in the case of chitosan and nanocomposite coatings were reduced by 53% and 63%, respectively. The nanocomposite coating showed a 2-fold reduction in total fungal concentrations in comparison to the chitosan treated samples. Results demonstrate the effectiveness of the nanocomposite coatings for the reduction of fungal and bacterial growth in the okra samples after 12 storage days. The nanocomposite coatings did not affect the quality attributes of the okra, such as pH, total soluble solids, moisture content, and weight loss. This work demonstrates that the chitosan-ZnO nanocomposite coatings not only maintains the quality of the packed okra but also retards microbial and fungal growth. Thus, chitosan-ZnO nanocomposite coating can be used as a potential coating material for active food packaging applications.

63 citations


Journal ArticleDOI
TL;DR: Polymer flooding displacement ability during petroleum extraction from the earth's crust plays an important role in enhanced oil recovery processes as discussed by the authors, and produced water, as a byproduct, still contain high levels of hydrogen.

49 citations


Journal ArticleDOI
TL;DR: Finite element models are used to show the extent and nature of electric field modulation, associated with changes in the size, thickness, and permittivity of commonly used nanostructured dielectric coatings such as zinc oxide (ZnO) and titanium dioxide (TiO2).
Abstract: The magnitude and distribution of the electric field between two conducting electrodes of a capacitive deionization (CDI) device plays an important role in governing the desalting capacity. A dielectric coating on these electrodes can polarize under an applied potential to modulate the net electric field and hence the salt adsorption capacity of the device. Using finite element models, we show the extent and nature of electric field modulation, associated with changes in the size, thickness, and permittivity of commonly used nanostructured dielectric coatings such as zinc oxide (ZnO) and titanium dioxide (TiO2). Experimental data pertaining to the simulation are obtained by coating activated carbon cloth (ACC) with nanoparticles of ZnO and TiO2 and using them as electrodes in a CDI device. The dielectric-coated electrodes displayed faster desalting kinetics of 1.7 and 1.55 mg g–1 min–1 and higher unsaturated specific salt adsorption capacities of 5.72 and 5.3 mg g–1 for ZnO and TiO2, respectively. In cont...

16 citations


Journal ArticleDOI
TL;DR: In this article, an experimental study of the dynamic range maximization with Zinc Oxide (ZnO) nanorods coated glass substrates for humidity and vapor sensing is reported.
Abstract: An experimental study of the dynamic range maximization with Zinc Oxide (ZnO) nanorods coated glass substrates for humidity and vapor sensing is reported. Growth time of the nanorods and the length ...

14 citations


Journal ArticleDOI
TL;DR: The ZnO NRs grown on various optical surfaces are promising broadband saturable absorbers for nanosecond near-IR lasers in bulk and waveguide geometries and at low saturation intensity and high fraction of the saturable losses.
Abstract: Zinc oxide (ZnO) nanorods (NRs) oriented along the crystallographic [001] axis are grown by the hydrothermal method on glass substrates. The ZnO NRs exhibit a broadband (1-2 µm) near-IR absorption ascribed to the singly charged zinc vacancy VZn-1. The saturable absorption of the ZnO NRs is studied at ≈1 µm under picosecond excitation, revealing a low saturation intensity, ≈10 kW/cm2, and high fraction of the saturable losses. The ZnO NRs are applied as saturable absorbers in diode-pumped Yb (≈1.03 µm) and Tm (≈1.94 µm) lasers generating nanosecond pulses. The ZnO NRs grown on various optical surfaces are promising broadband saturable absorbers for nanosecond near-IR lasers in bulk and waveguide geometries.

7 citations


Journal ArticleDOI
TL;DR: It is demonstrated that the immune response is strongly dependent on the surface functionalities of the SiO2 NS, rendering them an attractive material for the development of future immunological therapies.

3 citations


Journal ArticleDOI
TL;DR: Capacitive deionization (CDI) is an upcoming technique that can replace existing processes for removing and recuperating metal ions from dilute industrial waste waters as mentioned in this paper, which removes ions via electro...
Abstract: Capacitive deionization (CDI) is an upcoming technique that can replace existing processes for removing and recuperating metal ions from dilute industrial waste waters. CDI removes ions via electro ...

1 citations


Patent
27 Dec 2018
TL;DR: In this article, a device for capacitive deionization of an aqueous media containing dissolved ion species is described, consisting of a cell with a first primary electrode and a second primary electrode.
Abstract: A device (10) for capacitive deionization of an aqueous media containing dissolved ion species, said device comprising a cell with a first primary electrode (2) and a second primary electrode (3) a ...

1 citations