M
Mingfei Zhou
Researcher at Fudan University
Publications - 328
Citations - 8375
Mingfei Zhou is an academic researcher from Fudan University. The author has contributed to research in topics: Infrared spectroscopy & Matrix isolation. The author has an hindex of 43, co-authored 313 publications receiving 7404 citations. Previous affiliations of Mingfei Zhou include National Institute of Advanced Industrial Science and Technology & Ames Research Center.
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Spectroscopic and theoretical investigations of vibrational frequencies in binary unsaturated transition-metal carbonyl cations, neutrals, and anions.
TL;DR: The laser-ablation method produces mostly neutral atoms with a few percent cations and electrons for capture to make anions; in contrast, thermal evaporation gives only neutral species, so the very recent neon matrix investigations in the laboratory provide carbonyl cation and anions for comparison to neutrals on a level playing field.
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Spectroscopic and theoretical studies of transition metal oxides and dioxygen complexes.
TL;DR: This work has highlighted the importance of knowing the carrier and removal status of materials before they are exposed to each other in the intermediate stages of decomposition.
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OCBBCO: A neutral molecule with some boron-boron triple bond character
TL;DR: Experimental and theoretical evidence is reported of a neutral OCBBCO molecule with some boron-boron triple bond character that was produced and unambiguously characterized by matrix isolation infrared spectroscopy.
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Observation of alkaline earth complexes M(CO)8 (M = Ca, Sr, or Ba) that mimic transition metals
Xuan Wu,Lili Zhao,Jiaye Jin,Sudip Pan,Wei Li,Xiaoyang Jin,Guanjun Wang,Mingfei Zhou,Gernot Frenking,Gernot Frenking +9 more
TL;DR: Analysis of the electronic structure of these cubic Oh-symmetric complexes reveals that the metal–carbon monoxide (CO) bonds arise mainly from [M(dπ)] → (CO]8 π backdonation, which explains the strong observed red shift of the C-O stretching frequencies.
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Identification of an iridium-containing compound with a formal oxidation state of IX
Guanjun Wang,Mingfei Zhou,James T. Goettel,Gary J. Schrobilgen,Jing Su,Jun Li,Tobias Schlöder,Sebastian Riedel +7 more
TL;DR: Quantum-chemical calculations are carried out at the highest level of theory, and predict that the iridium tetroxide cation, with a Td-symmetrical structure and a d0 electron configuration, is the most stable of all possible [IrO4]+ isomers.