S
Stephen Hanessian
Researcher at Université de Montréal
Publications - 764
Citations - 19319
Stephen Hanessian is an academic researcher from Université de Montréal. The author has contributed to research in topics: Total synthesis & Bicyclic molecule. The author has an hindex of 65, co-authored 754 publications receiving 18572 citations. Previous affiliations of Stephen Hanessian include Parke-Davis & University of California, Irvine.
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1,3-Asymmetric Induction in Dianionic Allylation Reactions of Amino Acid Derivatives — Synthesis of Functionally Useful Enantiopure Glutamates, Pipecolates and Pyroglutamates.
TL;DR: In this paper, the roles of protecting groups and of the electrophile were studied in N-Cbz and N-Boc glutamic acid esters and their potential utility in peptidomimetic design was also described.
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Kinetic Diastereomer Differentiation in Au(III)- and Bi(III)-Catalyzed Benzylic Arylation: Concise and Stereocontrolled Synthesis of 2-Amino-1,1-diarylalkanes.
TL;DR: In this paper, a stereocontrolled Friedel-based alkylation with electron-rich arenes in the presence of AuCl3 or Bi(OTf)3 as the catalyst is described.
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Efficient Olefination with α-Alkyl Cyclic Phosphonamides.
TL;DR: In this paper, a variety of acyclic and cyclic aldehydes and ketones can be converted into corresponding alkylidene, benzylidene and methoxycarbonyl alkene derivatives by treatment with 1,3,2-diazaphospholidine-2,alkyl-1,3-dimethyl 2-oxides (α-alkyl cyclic phosphonamides) under mild conditions.
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Catalytic properties of 4,5-bridged proline methano- and ethanologues in the Hajos–Parrish intramolecular aldol reaction
TL;DR: In this article , the catalysis of the Hajos-Parrish reaction by cis-and trans-4,5-ethano-proline was explored experimentally and computationally with DFT (ωB97X-D and MN15) and DLPNO-CCSD(T).
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Highly Stereocontrolled Sequential Asymmetric Michael Addition Reactions with Cinnamate Esters - Generation of Three and Four Contiguous Stereogenic Centers on Seven-Carbon Acyclic Motifs.
TL;DR: In this paper, allyl and crotyl bicyclic chiral phosphonamide anions with two cinnamate esters leads to a sequential Michael reaction with excellent diastereoselectivity.