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Tolstikov Genrikh A

Researcher at Russian Academy of Sciences

Publications -  1346
Citations -  5730

Tolstikov Genrikh A is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Catalysis & Ozonolysis. The author has an hindex of 27, co-authored 1346 publications receiving 5222 citations. Previous affiliations of Tolstikov Genrikh A include Bashkir State University.

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Synthetic transformations of isoquinoline alkaloids. 1-alkynyl-3,6-dimethoxy-N-methyl-4,5α-epoxy-6,18-endoethenobenzo[i]isomorphinans and their transformations

TL;DR: The Mannich reaction of dihydrothebainehydroquinone with piperazine and anabasine in the presence of formaldehyde was catalyzed by copper(I) compounds as discussed by the authors.
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Acetylenic derivatives of betulonic acid amide as a new type of compounds possessing spasmolytic activity

TL;DR: In this article, an efficient and versatile synthetic procedures towards novel derivatives of betulonic acid via Mannich reaction, Sonogashira cross-coupling, and copper(i)-catalyzed 1,3-dipolar cyclo-additions were developed.
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New method for dehydrogenation of 1,4-dihydropyridines to pyridines using homogeneous complex palladium catalysts

TL;DR: In this paper, it was shown that 2,6-dimethyl-3,5-dicarbethoxy-1,4-dihydropyridine and its 4-substituted alkyl derivatives are easily converted to the corresponding pyridines under the influence of homogeneous Pd catalysts.
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A Convenient Approach to the Synthesis of Glycosphingolipids via the Acidic Decyclization of Hexo-O-acetyl-d-gentiobial

TL;DR: In this paper, the mercury sulphate catalysed acidic opening of the dihydropyran ring in hexa-O -acetyl-D -gentiobial 2, resulting in (2 E,4 S,5 R )-4-acetoxy-5-hydroxy-6-(2,3,4,6-tetra- O-acetyl -β-D-glucopyranosyloxy)hex-2-enal 3 was employed as the key transformation in the synthesis of O -glycosides, which are prec
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Kinetic stereocontrol of polydiene microstructures during polymerization of Nd-Al bimetallic systems

TL;DR: In this paper, the authors investigated the kinetics of the propagation reaction and the polybutadiene microstructure using a low initial concentration of the monomer and derived an expression connecting the ratio of the formation rates for 1,4- cis and 1, 4- trans units to the current monomer concentration.