Institution
Nanchang Hangkong University
Education•Nanchang, China•
About: Nanchang Hangkong University is a education organization based out in Nanchang, China. It is known for research contribution in the topics: Microstructure & Alloy. The organization has 7004 authors who have published 5270 publications receiving 62162 citations. The organization is also known as: Nanchang Aviation University.
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TL;DR: The characterization results indicated that La and Ce doping induced obvious crystal phase transformation in Bi2O3, from monoclinic to tetragonal phase, which showed much higher photocatalytic performance than that of bare Bi2 O3, single La or Ce doped Bi 2O3 samples.
Abstract: A series of La/Ce-codoped Bi2O3 composite photocatalysts were fabricated via hydrothermal–calcination process. The as-prepared products were intensively characterized by some physicochemical characterizations like N2 physical adsorption, X-ray powder diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), UV–Vis diffuse reflectance (UV–Vis DRS), Fourier transform infrared spectroscopy (FT-IR), photoelectrochemical measurements, and photoluminescence (PL) spectroscopy. The characterization results indicated that La and Ce doping induced obvious crystal phase transformation in Bi2O3, from monoclinic to tetragonal phase. La and Ce codoping also gave rise to the obvious synergetic effects, e.g., the lattice contraction of Bi2O3, the decrease of crystal size and the increase of surface area. The photocatalytic performance of the prepared catalysts was evaluated by removal of dye acid orange II with high concentration under visible light irradiation. Results showed that La/Ce-codoped Bi2O3 displayed much higher photocatalytic performance than that of bare Bi2O3, single La or Ce doped Bi2O3 samples. The superior photocatalytic activity was mainly attributed to the improved texture and surface properties and the synergistic effects of La and Ce codoping on suppressing the recombination of photo-generated electrons (e−) and holes (h+).
34 citations
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TL;DR: In this article, a magnetic Cu(II) ion-imprinted polymer was used for the rapid enrichment of trace quantities of copper ions in environmental water, and the results showed that the detection limit and enrichment factor were 0.3μg L−1 and 100, respectively.
Abstract: We have developed a convenient, selective and reliable method for the rapid enrichment of trace quantities of Cu(II) by using a magnetic Cu(II) ion-imprinted polymer. This is followed by their determination by FAAS. The imprints were prepared by using (a) Cu(II) ions as the template, (b) 3-aminopropyltriethoxysilane as both the functional monomer and the crosslinking agent, and (c) Fe3O4 as the magnetic component. Enrichment is carried out in a single step, and adsorbed copper ions can be separated from the sample solution by applying a strong magnet. The effects of pH, elution condition, amount of imprint, and of potentially interfering ions were evaluated. Under the optimal conditions, the detection limit and enrichment factor are 0.3 μg L−1 and 100, respectively, and the recovery is >95 %. The procedure was successfully applied in the enrichment and detection of trace copper ions in environmental water.
34 citations
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TL;DR: In this article, the authors proposed a utility function for complexity and its curve is drawn according to the mutual relationship between the complexity and utility, and the underlying trend that the system becomes more and more complex in an everchanging environment is analyzed in terms of the variation of complexity with time.
34 citations
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TL;DR: In this paper, the initial atmospheric corrosion of carbon steels over a one-month period in six outdoor dynamic atmospheric environments in China was investigated based on the ∼250,000 corrosion data sets collected, and the environmental impacts of relative humidity, temperature and rainfall on the initial corrosion behavior was investigated.
34 citations
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TL;DR: In this paper, a single-crystal X-ray diffraction of N-(2-cyanoethyl) glycine and NaN3 with corresponding metal salts yielded three energetic coordination polymers: [Zn(tzeg)]n1 and [M(tzEG)(H2O)]n (M = Cd2+ for 2, Cu2+for 3) (H2tzeg = N-[2-(1H-tetrazol-5-yl)ethyl]glycine).
Abstract: Hydrothermal reaction of N-(2-cyanoethyl)glycine and NaN3 with corresponding metal salts yielded three energetic coordination polymers: [Zn(tzeg)]n1 and [M(tzeg)(H2O)]n (M = Cd2+ for 2, Cu2+ for 3) (H2tzeg = N-[2-(1H-tetrazol-5-yl)ethyl]glycine), which were characterized by single-crystal X-ray diffraction. Nitrogen-rich tzeg2− ligand is a new in situ generated organic compound through [2 + 3] cycloaddition reaction of nitrile and azide, which adopts two different coordination modes in 1–3. Polymer 1 features an achiral 3D network built up by interweaving of left/right-handed helical channels. Isostructural 2 and 3 exhibit an achiral 2D network formed alternately by left/right-handed helical chains. As nitrogen-rich energetic materials, 1 and 3 possess higher enthalpies of combustion (ΔHc), which are −12.054 and −11.583 kJ g−1, respectively, than the classical energetic compounds 1,3,5-trinitro-1,3,5,-triazine (RDX, −9.6 kJ g−1) and 1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX, −9.44 to −9.88 kJ g−1). The solid-state excitation and emission spectra for 1–3 were investigated at room temperature, which reveals ligand-centered luminescent emissions in the intensity order of 2 > 1 > 3. Variable-temperature magnetic susceptibility data show that 3 displays a weak antiferromagnetic interaction mainly resulting from magnetic exchange coupling between Cu2+ ions through double tetrazolato bridges.
34 citations
Authors
Showing all 7046 results
Name | H-index | Papers | Citations |
---|---|---|---|
Jinghong Li | 112 | 465 | 48474 |
Chi Zhang | 88 | 1545 | 38876 |
Feng Ding | 85 | 485 | 20354 |
Zhongping Chen | 81 | 742 | 24249 |
Xiaoming Liu | 78 | 745 | 24988 |
Lin Guo | 77 | 414 | 18999 |
Zhenhai Wen | 73 | 267 | 18380 |
Tong Wu | 66 | 591 | 19325 |
Xin Lu | 63 | 371 | 13739 |
Junwang Tang | 62 | 223 | 16059 |
Chak Tong Au | 61 | 298 | 12525 |
Qiang Liu | 60 | 652 | 20634 |
Shenglian Luo | 60 | 182 | 10509 |
Guo-Cong Guo | 60 | 439 | 12268 |
Paul L. Rosin | 59 | 391 | 13094 |