Naval Surface Warfare Center

About: Naval Surface Warfare Center is a facility organization based out in Washington D.C., District of Columbia, United States. It is known for research contribution in the topics: Radar & Sonar. The organization has 2855 authors who have published 3697 publications receiving 83518 citations. The organization is also known as: NSWC.

Structural Changes of Cobalt-Based Perovskites upon Water Oxidation Investigated by EXAFS

Abstract: While many perovskites remain crystalline during the oxygen evolution reaction (OER) in alkaline media, some highly active perovskites become amorphous. We studied the local structure changes of perovskites LaCoO3, Ba0.5Sr0.5Co0.8Fe0.2O3-δ, and SrCo0.8Fe0.2O3-δ before and after OER by X-ray absorption spectroscopy. No change in either local structure or OER activity was observed for LaCoO3, while considerably enhanced OER activities and the conversion of the local structure from corner-sharing octahedra to edge-sharing octahedra were noted for Ba0.5Sr0.5Co0.8Fe0.2O3-δ and SrCo0.8Fe0.2O3-δ as a result of the OER. Possible processes responsible for the structural change and enhanced OER activities are discussed.

Effect of quenching on the magnetostriction on Fe/sub 1-x/Ga/sub x/ (0.13x<0.21)

Abstract: The magnetostriction (/spl lambda//sub 100/) of b.c.c. Fe is increased over 10-fold at room temperature by the substitution of /spl sim/20% gallium for Fe. Fe/sub 1-x/Ga/sub x/ alloys with x between 0.19 and 0.214 that are quenched from 800/spl deg/C exhibit magnetostrictions /spl sim/25% higher than those furnace-cooled at 10/spl deg//min. We propose that this great increase of magnetostriction above that of Fe in Fe-Ga alloys is not due to conventional magnetoelastic effects but due to the substitutive presence of asymmetrically shaped clusters of the Ga atoms. As the concentration of solute atoms approaches 25%, the lattice becomes relaxed with formation of a more ordered structure and the magnetostriction decreases in value.

Designing for ultrahigh-temperature applications: The mechanical and thermal properties of HfB2, HfcX, HfNX and αHf(N)

Abstract: The thermal conductivity, thermal expansion, Young's Modulus, flexural strength, and brittle-plastic deformation transition temperature were determined for HfB2, HfC0.98, HfC0.67, and HfN0.92 ceramics. The mechanical behavior of αHf(N) solid solutions was also studied. The thermal conductivity of modified HfB2 exceeded that of the other materials by a factor of 5 at room temperature and by a factor of 2.5 at 820°C. The transition temperature of HfC exhibited a strong stoichiometry dependence, decreasing from 2200°C for HfC0.98 to 1100°C for HfC0.67 ceramics. The transition temperature of HfB2 was 1100°C. Pure HfB2 was found to have a strength of 340 MPa in 4 point bending, that was constant from room temperature to 1600°C, while a HfB2 + 10% HfCx had a higher room temperature bend strength of 440 MPa, but that dropped to 200 MPa at 1600°C. The data generated by this effort was inputted into finite element models to predict material response in internally heated nozzle tests. The theoretical model required accurate material properties, realistic thermal boundary conditions, transient heat transfer analysis, and a good understanding of the displacement constraints. The results of the modeling suggest that HfB2 should survive the high thermal stresses generated during the nozzle test primarily because of its superior thermal conductivity. The comparison the theoretical failure calculations to the observed response in actual test conditions show quite good agreement implying that the behavior of the design is well understood.

An amplitude Modulation detector for fault diagnosis in rolling element bearings

Abstract: The purpose of this research is to identify single-point defects in rolling element bearings. These defects produce characteristic fault frequencies that appear in the machine vibration and tend to modulate the machine's frequencies of mechanical resonance. An amplitude modulation (AM) detector is developed to identify these interactions and detect the bearing fault while it is still in an incipient stage of development (i.e., to detect the instances of AM when the magnitude of the characteristic fault frequency itself is not significant). Use of this detector only requires machine vibration from one sensor and knowledge of the bearing characteristic fault frequencies. Computer simulations as well as machine vibration data from bearings containing outer race faults are used to confirm the proficiency of this proposed technique.