Showing papers in "Journal of Inorganic and Nuclear Chemistry in 1970"

TL;DR: In this paper, the triheteropolyanions XZ W 11 O 40 H 2 n − ( x = B, Zn, P, Si, Ge; Z = Cu II, Mn II, Mn III ), XZ Mo 11 O40 H 2n − ( X = P, si, Ge, Z = Mn II, Cu II ), and X 2 ′CuW 17 O 62 H 2 8− (X ′ = As) are reported.

TL;DR: In this paper, an explanation for the tetrad effect in the Z, or q, dependence of various physical and chemical properties of some complexes in the lanthanide (III) or actinide(III) series was proposed.

TL;DR: In this article, phase relations in the system CaO-cobalt oxide in air have been determined in the temperature range of approximately 800-1500°C, where the only crystalline phases existing in equilibrium with liquids are lime solid solution and CoO solid solution; eutectic temperature in air is 1350°C.

TL;DR: The dependence of the wavenumbers of these vibrations on certain properties of the ions M and X is discussed in this paper, where the dependence of those vibrations on the properties of these ions is discussed.

TL;DR: In this paper, two types of structure stability fields were constructed using effective ionic radii, which can be used to predict the radii of certain cations and the effects of high pressure on structure.

TL;DR: In this article, the spectral properties of the electron transfer complexes of [MN 6 ] type, [Cr(bipy) 3 ] z, where z = +3, +2, +1, 0 and bipy = 2,2′-bipyridyl, are reported between 5000 and 50,000 cm −1.

TL;DR: The ir and Raman spectra of several complexes of europium(III) β-diketonates have been observed as mentioned in this paper, and it has been found that all the spectra can be interpreted, to a good approximation, by considering a single chelate ring withy a local C 2 v symmetry.

TL;DR: In this paper, a ternary phase diagram was constructed between UO 2 -U 3 O 8 and CeO 2 −CeO 1·818 for all concentrations of Ce and for temperatures between room temperature and 600°C, from results obtained using a high-temperature X-ray powder diffraction camera.

TL;DR: In this paper, the chlorides of metal ions with derivatives of group VA elements which are solid at room temperature and melt well below the decomposition temperature of the corresponding complex are investigated.

TL;DR: In this paper, the phase relationships existing in the uranium-oxygen system at temperatures to 1600°C and pressures to 60 kb are reported and the crystal symmetry of α-U 2 O 5 is unknown.

TL;DR: In this article, the formation constant of the reaction (Cu A) 2+ + L − ⇌ (Cu AL ) + where A = dipyridyl and L = Glycine, α or β-alanine.

TL;DR: The equilibrium distributions of actinide and lanthanide elements between liquid bismuth solutions and a variety of LiF-containing molten fluoride salts were determined between 500 and 700°C as mentioned in this paper.

TL;DR: Alkaline earth chloroborates and bromobors have been synthesized and found to exhibit a stoichiometry and crystal structure different from that of magnesium boracite as mentioned in this paper.

TL;DR: In this paper, the distribution of acetic, n-propionic and n-butyric acids between various organic solvents and 0·10 M (Na, H)ClO 4 solution has been studied at 25°C.

TL;DR: In this article, the preparation of salicylaldazinate (SAA) metal complexes of Cu(II, Ni(II), Co(II) and Fe(II).

TL;DR: In this article, the absorption spectra of the uranium(V) ions in concentrated chloride solutions and in aqueous carbonate solutions have been measured, and the concentration of these solutions has been determined.

TL;DR: In this article, the stability of the monoacetate complexes of trivalent Ce, Eu, Am, Cm, Bk and Cf have been determined by a solvent extraction technique in a 2·0 M (NaClO4) ionic medium.

TL;DR: In this paper, the interaction of arginine, citrulline, and ornithine with metal ions has been studied by potentiometric measurement of hydrogen ion concentration at 25° and ionic strengths of 0·10 and 1·0 M.

TL;DR: A gas equilibrium method has been used to obtain thermodynamic data at 800-950°C for substoichiometric uranium-cerium oxides (U1−zCezI−y) where 0·10 < z < 0·75 as mentioned in this paper.

TL;DR: The ionic medium method was used to investigate polyborate equilibria in aqueous NaCl, KCl, Na 2 SO 4, and CsI solutions from 25-90°C as mentioned in this paper.

TL;DR: In this paper, it has been established that most of the complexes of the following pairs of lanthanides: Ce, Pr, Sm, Eu, Tb, Dy, Tm, Yb, and actinides: Bk, Cf; show an extra stability in comparison to that resulting from linear interpolation between the following elements.

TL;DR: In this paper, the half-life and alpha particle energy of 147Sm and 149Sm were measured using a high-resolution cylindrical ionization chamber and the results were consistent with those obtained independently by Korolev.

TL;DR: In this article, the dehydration characteristics of two exchanged phases of crystalline α-zirconium phosphate have been determined, and the half-exchanged phase, Zr(NaPO 4 (HPO 4 · 5H 2 O), was found to form two lower hydrates and an anhydrous phase.

TL;DR: The adsorption of kurchatovium chloride on surfaces of glass and potassium chloride was studied by a gas-solid chromatographic technique as mentioned in this paper, and the compound was shown to be similar in its properties to hafnium tetrachloride.

TL;DR: In this paper, an adiabatic vacuum calorimeter has been used to measure the heat capacity of the trisacetylacetonato (TAC) complexes of scandium, vanadium, manganese, iron, and cobalt.