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A new constitutive equation derived from network theory

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TLDR
In this paper, a constitutive equation is derived from a Lodge-Yamamoto type of network theory for polymeric fluids, where the network junctions are not assumed to move strictly as points of the continuum but allowed a certain "effective slip".
Abstract
A constitutive equation is derived from a Lodge—Yamamoto type of network theory for polymeric fluids. The network junctions are not assumed to move strictly as points of the continuum but allowed a certain “effective slip”. The rates of creation and destruction of junctions are assumed to depend on the instantaneous elastic energy of the network, or equivalently, the average extension of the network strand, in a simple manner. Agreement between model predictions and the I.U.P.A.C. data on L.D.P.E. is good.

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Citations
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Journal ArticleDOI

Numerical study of secondary flows of viscoelastic fluid in straight pipes by an implicit finite volume method

TL;DR: In this paper, a general class of viscoelastic model is used to investigate numerically the pattern and strength of the secondary flows in rectangular pipes as well as the influence of material parameters on them.
Book

Non-Newtonian Fluid Mechanics

G. Böhme
TL;DR: In this paper, the authors present a set of formal formulas for special curvilinear coordinates for continuous fluid flow and show that they can be used to describe the normal stress functions of normal stress differences.
Journal ArticleDOI

Finite-element Analysis of Die Swell of a Highly Elastic Fluid

TL;DR: In this article, a mixed finite element method is applied to the die swell calculation of ana Oldroyd fluid B. The use of large entry lengths together with the presence of the retardation time in the constitutive equations allow us to reach values of the recoverable shear as high as four for the flow emerging from slit and circular dies, with swelling ratios of the order of 2.
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A constitutive analysis of uniaxial elongational flow data of low-density polyethylene melt

TL;DR: In this article, the uniaxial elongational flow data of a well-characterized LDPE melt were analyzed in terms of a single integral constitutive equation, which has already been successfully used to described shear flow experiments of the same polymer melt.
References
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Journal ArticleDOI

Conservation Laws for Liquid Crystals

Journal ArticleDOI

The Visco-elastic Properties of Network Structure I. General Formalism

TL;DR: In this article, the authors derived the stress-strain-time (S − S − T )relation at each instance of macroscopic observations by using the statistical mechanical considerations of equilibrium states.
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Constitutive equations from molecular network theories for polymer solutions

TL;DR: In this article, constitutive equations based on the network models of Yamamoto, Lodge, and Kaye are re-derived in a common notation involving the use of base vectors embedded in the deforming macroscopic continuum.
Journal ArticleDOI

Anisotropic Fluid Theory: A Different Approach to the Dumbbell Theory of Dilute Polymer Solutions

TL;DR: In this paper, the authors used the continuum theory of anisotropic fluids, as developed by Ericksen and others, to formulate an expression for the time derivative of the end-to-end vector of a linear macromolecule when used in conjunction with the equation describing the distribution function for a dilute solution of dumbbell elements.