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A new constitutive equation derived from network theory

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TLDR
In this paper, a constitutive equation is derived from a Lodge-Yamamoto type of network theory for polymeric fluids, where the network junctions are not assumed to move strictly as points of the continuum but allowed a certain "effective slip".
Abstract
A constitutive equation is derived from a Lodge—Yamamoto type of network theory for polymeric fluids. The network junctions are not assumed to move strictly as points of the continuum but allowed a certain “effective slip”. The rates of creation and destruction of junctions are assumed to depend on the instantaneous elastic energy of the network, or equivalently, the average extension of the network strand, in a simple manner. Agreement between model predictions and the I.U.P.A.C. data on L.D.P.E. is good.

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Citations
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Three dimensional numerical simulations of viscoelastic flows through planar contractions

TL;DR: In this article, a 3D finite volume method with the primary variable elastic viscous split stress (EVSS) formulation is employed, and a very efficient 3D block solver coupled with block correction is developed to speed up the convergence rate.
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Zur Netzwerktheorie von Polymer-Schmelzen

TL;DR: Theorie der „gummiartigen“ Flussigkeit stellt bei kleinen Deformationen eine korrekte Beschreibung des rheologischen Verhaltens polymerer Losungen and Schmelzen dar as mentioned in this paper.
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A new microstructure-based constitutive model for human blood

TL;DR: In this paper, a new constitutive equation for whole human blood is derived using ideas drawn from temporary polymer network theory to model the aggregation and disaggregation of erythrocytes in normal human blood at different shear rates.
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Nonlinear Shear and Extensional Flow Dynamics of Wormlike Surfactant Solutions

TL;DR: In this paper, the effects of surfactant (EHAC) and salt (NH4Cl) concentrations on the linear viscoelastic parameters are determined using small amplitude oscillatory shear experiments, and the steady and time-dependent shear rheology is determined in a double gap Couette cell, and transient extensional flow measurements are performed in a capillary breakup extensional rheometer.
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Finite element simulation of viscoelastic flow

TL;DR: In this article, the memory kernel is chosen to be a single exponential in the time lapse (Maxwell model) and the formulation is such that it can easily be generalized to more realistic models such as the BKZ theory.
References
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Journal ArticleDOI

Conservation Laws for Liquid Crystals

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The Visco-elastic Properties of Network Structure I. General Formalism

TL;DR: In this article, the authors derived the stress-strain-time (S − S − T )relation at each instance of macroscopic observations by using the statistical mechanical considerations of equilibrium states.
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Constitutive equations from molecular network theories for polymer solutions

TL;DR: In this article, constitutive equations based on the network models of Yamamoto, Lodge, and Kaye are re-derived in a common notation involving the use of base vectors embedded in the deforming macroscopic continuum.
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Anisotropic Fluid Theory: A Different Approach to the Dumbbell Theory of Dilute Polymer Solutions

TL;DR: In this paper, the authors used the continuum theory of anisotropic fluids, as developed by Ericksen and others, to formulate an expression for the time derivative of the end-to-end vector of a linear macromolecule when used in conjunction with the equation describing the distribution function for a dilute solution of dumbbell elements.