scispace - formally typeset
Journal ArticleDOI

A new constitutive equation derived from network theory

Reads0
Chats0
TLDR
In this paper, a constitutive equation is derived from a Lodge-Yamamoto type of network theory for polymeric fluids, where the network junctions are not assumed to move strictly as points of the continuum but allowed a certain "effective slip".
Abstract
A constitutive equation is derived from a Lodge—Yamamoto type of network theory for polymeric fluids. The network junctions are not assumed to move strictly as points of the continuum but allowed a certain “effective slip”. The rates of creation and destruction of junctions are assumed to depend on the instantaneous elastic energy of the network, or equivalently, the average extension of the network strand, in a simple manner. Agreement between model predictions and the I.U.P.A.C. data on L.D.P.E. is good.

read more

Citations
More filters
Journal ArticleDOI

Viscoelastic Flow Due to a Rotating Disc Enclosed in a Cylindrical Casing

TL;DR: In this article, the behavior of viscoelastic flows due to a rotating disc has been characterized based on an experimental study using a flow visualization technique and numerical simulation using several models for constitutive equations.
Journal ArticleDOI

Analysis and experiments on the spreading dynamics of a viscoelastic drop

TL;DR: In this article, a simplified Phan-Thien-Tanner (sPTT) model is considered to represent the rheology of a sessile viscoelastic drop on a horizontal surface.
Journal ArticleDOI

Numerical simulation of 3D viscoelastic developing flow and heat transfer in a rectangular duct with a nonlinear constitutive equation

TL;DR: In this article, the authors presented a 3D numerical simulation for developing viscoelastic duct flow that takes the dependency of flow parameters to the temperature into account, which is a common form of the Phan-Thien Tanner (PTT) model.
Journal ArticleDOI

Dispersion of a solute in a Poiseuille flow of a viscoelastic fluid

TL;DR: Gill and Sankarasubramanian's analysis of the dispersion of Newtonian fluids in laminar flow between two parallel walls is extended to the flow of non-Newtonian viscoelastic fluids (known as Phan-Thein-Tanner (PTT)) as discussed by the authors.
Journal ArticleDOI

Flash DSC crystallization study for blown film grade bimodal HDPE resins. I. Isothermal kinetics and its application of the blown film modeling

TL;DR: Isothermal ultra-cooling crystallization tests were conducted on three blown film grade bimodal HDPE resins using an ultrafast scanning calorimeter, the Flash DSC as discussed by the authors.
References
More filters
Journal ArticleDOI

Conservation Laws for Liquid Crystals

Journal ArticleDOI

The Visco-elastic Properties of Network Structure I. General Formalism

TL;DR: In this article, the authors derived the stress-strain-time (S − S − T )relation at each instance of macroscopic observations by using the statistical mechanical considerations of equilibrium states.
Journal ArticleDOI

Constitutive equations from molecular network theories for polymer solutions

TL;DR: In this article, constitutive equations based on the network models of Yamamoto, Lodge, and Kaye are re-derived in a common notation involving the use of base vectors embedded in the deforming macroscopic continuum.
Journal ArticleDOI

Anisotropic Fluid Theory: A Different Approach to the Dumbbell Theory of Dilute Polymer Solutions

TL;DR: In this paper, the authors used the continuum theory of anisotropic fluids, as developed by Ericksen and others, to formulate an expression for the time derivative of the end-to-end vector of a linear macromolecule when used in conjunction with the equation describing the distribution function for a dilute solution of dumbbell elements.