Journal ArticleDOI
A new sensitive structural motif inlaying the azides and tetrazole-based rigid 3D energetic MOFs: Highly sensitive primary explosives with excellent thermal stability
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In this article , the authors employed the rigid tetrazole ligand to obtain two 3D energetic metal-organic frameworks (EMOFs) [Cd3(N3)2(tz)3(OH)n 2 (Htz = tetrazoles).About:
This article is published in Chemical Engineering Journal.The article was published on 2022-02-01. It has received 18 citations till now. The article focuses on the topics: Tetrazole & Azide.read more
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Sensitive structural motifs separately distributed in azide-based 3D EMOFs: A primary explosive with excellent initiation ability and enhanced stability
Yun-Fan Yan,Tianhua Xu,Fei Wen,Yu Zhang,H.Y. Bian,Baoyi Li,Ning-Ning Zhang,Fa-Kun Zheng,Guo-Cong Guo +8 more
TL;DR: Azide-based energetic metal−organic frameworks (EMOFs) with remarkable initiation capability can be expected to replace lead-based primers (lead azide, LA; lead styphnate, LS) as discussed by the authors .
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Energetic coordination compounds of late 3d metals with 1N-(Nitromethyl)-5H-tetrazole, a ligand with astonishing properties from the rare class of N-nitromethyl azoles
TL;DR: In this paper , the N-nitromethyl moiety is introduced onto the 1,5H-tetrazole scaffold, representing the fourth and fifth ever synthesized N-Nitromethyl azoles.
Journal ArticleDOI
Facile synthesis and superior properties of a nitrogen-rich energetic Zn-MOF with a 2D azide-bridged bilayer structure.
TL;DR: In this paper , a new Pb-free energetic metal-organic frameworks (EMOFs) with both high nitrogen content and high thermostability was synthesized by simply using a commercial ligand (atz) under mild conditions.
Journal ArticleDOI
New form of high energy primary explosive: Dual structure composed of ionic salt-based coordination polymers
Tingwei Wang,Shu-Hui Bu,Zujia Lu,Baolong Kuang,Zhenxin Yi,Zhiming Xie,Chao Zhang,Yan Hong Li,Jianguo Zhang +8 more
TL;DR: Based on the guiding ideology of crystallization chemistry and synthetic chemistry, Wang et al. as mentioned in this paper put forward the concept of multi-structure CPs for the first time, and creatively designed two kinds of primary explosive Cu(PZCA)2(ClO4)2 (ECPs-1) and Cu(HAPZCA), 2 (ClO 4)4 (EIsCPs-1).
Journal ArticleDOI
Coordination polymerization of nitrogen-rich linkers and dicyanamide anions toward energetic coordination polymers with low sensitivities.
Haohui Xie,Qin Wang,Jiao-Lin Weng,Yun-Fan Yan,H.Y. Bian,Ying Huang,Fa-Kun Zheng,Renhui Qiu,Tianhua Xu +8 more
TL;DR: In this paper , the coordination polymerization of mild dicyanamide ions (DCA-), two isomeric ligands 1-methyl-5-aminotetrazole (1-MAT) and 2-methyl 5-amino-acetamide (2-MAT), was employed to construct energetic coordination polymers (ECPs).
References
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Journal ArticleDOI
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
TL;DR: Numerical calculations on a number of atoms, positive ions, and molecules, of both open- and closed-shell type, show that density-functional formulas for the correlation energy and correlation potential give correlation energies within a few percent.
Journal ArticleDOI
Multiwfn: a multifunctional wavefunction analyzer.
Tian Lu,Feiwu Chen +1 more
TL;DR: Five practical examples involving a wide variety of systems and analysis methods are given to illustrate the usefulness of Multiwfn, a multifunctional program for wavefunction analysis.
Journal ArticleDOI
SHELXT - Integrated space-group and crystal- structure determination
TL;DR: This work automates routine small-molecule structure determination starting from single-crystal reflection data, the Laue group and a reasonable guess as to which elements might be present.
Journal ArticleDOI
Revealing noncovalent interactions.
Erin R. Johnson,Shahar Keinan,Paula Mori-Sánchez,Julia Contreras-García,Aron J. Cohen,Weitao Yang +5 more
TL;DR: This work develops an approach to detect noncovalent interactions in real space, based on the electron density and its derivatives, which provides a rich representation of van der Waals interactions, hydrogen bonds, and steric repulsion in small molecules, molecular complexes, and solids.
Journal ArticleDOI
3D energetic metal-organic frameworks: synthesis and properties of high energy materials.
TL;DR: This work explores the preparation of halogen-free energetic 3D MOFs and replaces the hydrazine ligand with 4,4’-azo1,2,4-triazole (atrz), which showed a considerable reduction to the sensitivity, however, concomitantly their heats of detonation decreased.