Journal ArticleDOI
A theory of electrode reactions through bridge transition states; bridges with a discrete electronic spectrum
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In this paper, a theory has been developed for outer-sphere non-adiabatic electron transfer reactions at electrodes, to or from which an electron is transferred via ionic or molecular bridge species adsorbed on the electrode surface.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1972-09-01. It has received 81 citations till now. The article focuses on the topics: Marcus theory & Electron transfer.read more
Citations
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The effect of electrolyte composition on the electroreduction of CO2 to CO on Ag based gas diffusion electrodes
Sumit Verma,Sumit Verma,Xun Lu,Sichao Ma,Sichao Ma,Richard I. Masel,Paul J. A. Kenis,Paul J. A. Kenis +7 more
TL;DR: If the addition of KCl to such solutions can improve conductivity and hence jCO is investigated, Electrolytes containing KCl in combination with EMIM Cl, choline Cl, or DESs showed a two to three fold improvement in jCO in comparison to those without KCl.
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The influence of alkali metal cations on the rate of the Fe(CN)64−/Fe(CN)63− electrode process
TL;DR: In this article, the rate of the hexacyanoferrate redox system shows a first order dependence on the concentration of the cationic component of the supporting electrolyte.
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A nonadiabatic description of electron transfer reactions involving large free energy changes
TL;DR: In this article, the electron transfer reaction within a donor-acceptor, solvent separated ion pair (2A++2D·−) leading to excited singlet, excited triplet, and ground state products is studied within the framework of the theory of nonradiative transitions.
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Theory of charge transfer kinetics at solid-polar liquid interfaces
TL;DR: In this paper, a semi-phenomenological theory of charge transfer at solid-electrolyte solution interface was proposed, and the transition probability of transition between potential energy surfaces was investigated.
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Resonance and Environmental Fluctuation Effects in STM Currents through Large Adsorbed Molecules
TL;DR: In this paper, a new theoretical frame for scanning tunnelling microscopy (STM) processes is provided, based on perturbative coupling of the adsorbate levels to the substrate and tip.
References
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Journal ArticleDOI
On the Theory of Oxidation‐Reduction Reactions Involving Electron Transfer. I
TL;DR: In this paper, a mechanism for electron transfer reactions is described, in which there is very little spatial overlap of the electronic orbitals of the two reacting molecules in the activated complex, and a quantitative theory of the rates of oxidation reduction reactions involving electron transfer in solution is presented.
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Influence of cation adsorption on the kinetics of electrode processes
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On the determination of the value of the charge of the reacting particle and of the constant α from the dependence of the rate of electro-reduction on the potential and concentration of the solution☆
TL;DR: In this paper, it was shown that the only value that can be unambiguously determined from the dependence of the current strength on the concentration of the supporting electrolyte is the charge of the particles in the bulk of the solution that are in equilibrium with the transition state of the reaction.
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Kinetics of electron exchange between hexacyanoferrate(ii) and -(iii) ions.
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The Influence of Dielectric Saturation on the Thermodynamic Properties of Aqueous Ions
K. J. Laidler,C. Pegis +1 more
TL;DR: In this article, the authors apply the Born equation to the case of monatomic ions in aqueous solution, and give an interpretation of the experimental free energies and entropies that is more satisfactory than the simple model.