Journal ArticleDOI
Arylation de glycals catalysée par les sels de palladium: nouvelle synthèse de C-glycosides
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In this article, the arylation of peracetylated glycals catalyzed by palladium salts provides a new synthesis of C-glycosides, which is applied to several aromatic compounds, including fluoro and nitro...Abstract:
The arylation of peracetylated glycals catalyzed by palladium salts provides a new synthesis of C-glycosides. The title reaction is applied to several aromatic compounds, including fluoro and nitro...read more
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Book ChapterDOI
The chemistry and biochemistry of C-nucleosides and C-arylglycosides.
Hacksell U,Daves Gd +1 more
TL;DR: This chapter reviews recent advances in the chemistry and biochemistry of C-nucleosides, the literature concerning C-arylglycoside (i.e., nonnitrogen heterocyclic C- nucleoside) antibiotics, and recent significant advances in The most frequently used strategy for C-methine synthesis involves the construction of a heterocyClic aglycone from the C-1 substituent of a functionalized sugar intermediate.
Journal ArticleDOI
Total Synthesis of Aryl C-Glycoside Natural Products: Strategies and Tactics
TL;DR: The aryl C-glycoside structure is, among the plenty of biologically active natural products, one of the distinct motifs embedded, and the synthetic strategies and tactics employed in the total synthesis of this class of natural products.
Book ChapterDOI
Substitution-with-Allylic-Rearrangement Reactions of Glycal Derivatives
TL;DR: Glycals (or usually their O-substituted derivatives) are readily converted into 2,3-unsaturated glycosyl compounds with O-, C-, N-, S- or otherwise linked substituents at the anomeric position as discussed by the authors.