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Journal ArticleDOI

Behavior and mechanisms of Ni/ScSZ cermet anode deterioration by trace tar in wood gas in a solid oxide fuel cell

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TLDR
In this article, the authors examined the influence of tar concentration in wood gas on anode deterioration behavior by means of scanning electron microscopy and found that the anode degradation mechanism consisted of the disappearance of Ni particles, the destruction of sintered ScSZ, and carbon deposition.
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This article is published in International Journal of Hydrogen Energy.The article was published on 2011-05-01. It has received 32 citations till now. The article focuses on the topics: Tar & Solid oxide fuel cell.

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Use of gasification syngas in SOFC: Impact of real tar on anode materials

TL;DR: In particular, tars have been identified as one of the major impurities in biomass and coal gasification fuel gas, causing degradation of the anodes due to carbon deposition as discussed by the authors.
Journal ArticleDOI

An experimental study of the interaction between tar and SOFCs with Ni/GDC anodes

TL;DR: In this article, the effect of carbon dioxide that is capable of suppressing carbon deposition was experimentally investigated, and an enhanced performance was observed under the conditions studied, indicating that tar performs as fuel for SOFCs.
Journal ArticleDOI

The effect of heavy tars (toluene and naphthalene) on the electrochemical performance of an anode-supported SOFC running on bio-syngas

TL;DR: In this paper, the effect of heavy tar compounds on the performance of a Ni-YSZ anode supported solid oxide fuel cell was investigated, and both toluene and naphthalene were chosen as model compounds and tested separately with a simulated bio-syngas.
Journal ArticleDOI

Limiting factors for planar solid oxide fuel cells under different trace compound concentrations

TL;DR: In this article, the performance of anode supported solid oxide fuel cells under the influence of different trace compounds was investigated and the results showed how the ohmic contribution is almost independent of the H2S concentration.
Journal ArticleDOI

Biomass integrated gasifier-fuel cells: Experimental investigation on wood syngas tars impact on NiYSZ-anode Solid Oxide Fuel Cells

TL;DR: In this paper, the feasibility of a Biomass Integrated Gasifier Fuel Cell (B-IGFC) plant was evaluated with real wood syngas from a pilot batch gasifier.
References
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Journal ArticleDOI

Appraisal of Ce1−yGdyO2−y/2 electrolytes for IT-SOFC operation at 500°C

TL;DR: In this article, the authors evaluated thermodynamic and electrical conductivity data to select the most appropriate electrolyte composition for IT-SOFC operation at 500°C and found that the Gd 3+ ion is the preferred dopant, compared to Sm 3+ and Y 3+, at this temperature.
ReportDOI

Biomass Gasifier "Tars": Their Nature, Formation, and Conversion

TL;DR: In this article, the authors present the scientific and practical aspects of tar formation and conversion during gasification as a function of various technological and technical parameters and variables, and present a review of the most cumbersome and problematic parameter in any gasification commercialization effort.
Journal ArticleDOI

Electrical properties of ceria-based oxides and their application to solid oxide fuel cells

TL;DR: In this article, the ionic conductivities of samaria-doped ceria-alkaline-earth and rare-earth oxide systems were investigated in relation to their structures, electrical conductivities, and reducibilities.
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