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Journal ArticleDOI

BIOMASS ETHANOL: Technical Progress, Opportunities, and Commercial Challenges

Charles E. Wyman
- 01 Nov 1999 - 
- Vol. 24, Iss: 1, pp 189-226
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TLDR
In this article, the authors discuss the benefits of cellulose and hemicellulose fractions and the major challenges to realizing the great benefits of biomass ethanol without subsidies, and propose to use genetically engineered bacteria to ferment all five sugars in biomass to ethanol.
Abstract
▪ Abstract Ethanol made from lignocellulosic biomass sources, such as agricultural and forestry residues and herbaceous and woody crops, provides unique environmental, economic, and strategic benefits. Through sustained research funding, primarily by the U.S. Department of Energy, the estimated cost of biomass ethanol production has dropped from ∼$4.63/gallon in 1980 to ∼$1.22/gallon today, and it is now potentially competitive for blending with gasoline. Advances in pretreatment by acid-catalyzed hemicellulose hydrolysis and enzymes for cellulose breakdown coupled with recent development of genetically engineered bacteria that ferment all five sugars in biomass to ethanol at high yields have been the key to reducing costs. However, through continued advances in accessing the cellulose and hemicellulose fractions, the cost of biomass ethanol can be reduced to the point at which it is competitive as a pure fuel without subsidies. A major challenge to realizing the great benefits of biomass ethanol remains ...

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Citations
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Journal ArticleDOI

Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering.

TL;DR: Hydrogen Production by Water−Gas Shift Reaction 4056 4.1.
Journal ArticleDOI

Features of promising technologies for pretreatment of lignocellulosic biomass.

TL;DR: This paper reviews process parameters and their fundamental modes of action for promising pretreatment methods and concludes that pretreatment processing conditions must be tailored to the specific chemical and structural composition of the various, and variable, sources of lignocellulosic biomass.
Journal ArticleDOI

Microbial cellulose utilization: fundamentals and biotechnology.

TL;DR: A concluding discussion identifies unresolved issues pertaining to microbial cellulose utilization, suggests approaches by which such issues might be resolved, and contrasts a microbially oriented cellulose hydrolysis paradigm to the more conventional enzymatically oriented paradigm in both fundamental and applied contexts.
Journal ArticleDOI

Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited

TL;DR: An updated evaluation of potential target structures using similar selection methodology, and an overview of the technology developments that led to the inclusion of a given compound are presented.
Journal ArticleDOI

Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production

TL;DR: A review of various pretreatment process methods and the recent literature that has been developed can be found in this paper, where the goal of pretreatment is to make the cellulose accessible to hydrolysis for conversion to fuels.
References
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Book

Annual energy review

End Use
Journal ArticleDOI

Fuel ethanol from cellulosic biomass.

TL;DR: Ethanol produced from cellulosic biomass is examined as a large-scale transportation fuel and a cost-competitive process appears possible in a decade, with conversion economics the key obstacle to be overcome.
Book

Handbook on bioethanol : production and utilization

TL;DR: A review of pilot plant programs for bio-ethanol conversion from lignocellulosic biomass can be found in this article, where the authors discuss the economic, economic, and environmental issues for transportation fuels.
Journal ArticleDOI

Metabolic engineering of a pentose metabolism pathway in ethanologenic Zymomonas mobilis

TL;DR: This strain efficiently fermented both glucose and xylose, which is essential for economical conversion of lignocellulosic biomass to ethanol, and achieved through a combination of the pentose phosphate and Entner-Doudoroff pathways.
Journal ArticleDOI

OVERVIEW AND EVALUATION OF FUEL ETHANOL FROM CELLULOSIC BIOMASS: Technology, Economics, the Environment, and Policy

TL;DR: In this article, it is shown that ethanol may be more compatible with fuel cell-powered vehicles than has generally been assumed, and it is likely that vehicles can be configured so that exhaust emissions of priority pollutants are very low for ethanol-burning engines, although the same can probably be said for most other fuels under consideration.
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