Journal ArticleDOI
BioMOF-Mn: An Antimicrobial Agent and an Efficient Nanocatalyst for Domino One-Pot Preparation of Xanthene Derivatives.
TLDR
In this article , a new Mn-based metal-organic framework [UoB-6] was obtained via a one-step ultrasonic irradiation method with the ligand (H2bdda: 4,4'-(1,4-phenylenebis(azaneylylidene))bis(methaneyly lidene)dibenzoic acid).Abstract:
In this paper, a new Mn-based metal-organic framework [UoB-6] was obtained via a one-step ultrasonic irradiation method with the ligand (H2bdda: 4,4'-(1,4-phenylenebis(azaneylylidene))bis(methaneylylidene))dibenzoic acid. The structural integrity of the synthesized BioMOF-Mn was corroborated by FT-IR, EDX, ICP, XRD, TEM, DLS, FESEM, and BET-BJH analyses. The aerobic oxidative domino reaction of benzyl alcohols or aldehydes with dimedone derivatives was performed in the presence of the UoB-6 catalyst to produce xanthene derivatives in good yields. Hot filtration and Hg poisoning tests proved the heterogeneous nature of the catalyst. Novel synthesized xanthene-based bis-aldehydes were introduced as potent HDAC1 inhibitors according to molecular docking calculations. Finally, the inhibitory activities of Mn-MOF nanoparticles were evaluated on Escherichia coli and Candida albicans. The MIC, MBC, and MFC values were determined from 2048 to 4096 μg·mL-1 according to antimicrobial susceptibility testing methods. The inhibitory effects of antimicrobial agents can be exacerbated when loaded on BioMOFs.read more
Citations
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Nickel nanoparticles adorned on magnetized cellulose nanofibers: ultrasound-facilitated cross coupling reactions
Journal ArticleDOI
Value-added synthesized acidic polymer nanocomposite with waste chicken eggshell: A novel metal-free and heterogeneous catalyst for Mannich and hantzsch cascade reactions from alcohols
TL;DR: In this paper , a new nanocomposite material in which eggshell membranes act as nucleation sites for CoFe2O4 nanoparticle precipitation in the attendance of an external magnetic field was synthesized.
Journal ArticleDOI
CeO2 from pyrolysis of MOFs for efficient catalytic combustion of VOCs
TL;DR: Nano CeO2 (CeMOF) maintaining the primary micromorphology and pore structure of MOFs was successfully synthesized by controlled pyrolysis of UiO-66(Ce) in air as mentioned in this paper .
Journal ArticleDOI
Metal–Organic Frameworks and Their Biodegradable Composites for Controlled Delivery of Antimicrobial Drugs
TL;DR: A review of the state of the art in this highly topical area of research can be found in this article , where metal-organic frameworks (MOFs) and polymer-organic composites (POCs) are used as carriers and delivery agents of antimicrobial drugs.
Journal ArticleDOI
TiO2/g-C3N4/SO3H(IL): Unique Usage of Ionic Liquid-Based Sulfonic Acid as an Efficient Photocatalyst for Visible-Light-Driven Preparation of 5-HMF from Cellulose and Glucose.
Milad Nayebi,Amir Faraji,Ashkan Bahadoran,Zhian Jamal Othman,Soheila Arghavani,Pouya Ghamari Kargar,Seyed Mehrzad Sajjadinezhad,R. Varma +7 more
TL;DR: In this article , a morphologically unique acidic catalyst encompassing a two-dimensional (2D) TiO2/g-C3N4 heterojunction feature is described for the generation of 5-hydroxymethylfurfural (5-HMF), which exploits the acidic/ionic liquid (IL) bifunctional photocatalysis under visible light.
References
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Large-Pore Apertures in a Series of Metal-Organic Frameworks
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TL;DR: In this article, the authors present an extended cationic framework constructed from a single crystal isolated from the reaction mixture, which is shown to be stable in air and is insoluble in water and common organic solvents.
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Synthesis and applications of Rhodamine derivatives as fluorescent probes
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