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Carbon-rich organometallics: Application to molecular electronics
Munetaka Akita,Yuya Tanaka +1 more
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In this paper , the conductance behavior of a single molecule MMM junction based on carbon-rich organometallics has been investigated, with a particular focus on the mono-and oligo-nuclear, linear trans-Ru(phosphine)4-acetylide linkages.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2022-06-01. It has received 9 citations till now. The article focuses on the topics: Chemistry & Molecular electronics.read more
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High Seebeck Coefficient Achieved by Multinuclear Organometallic Molecular Junctions.
TL;DR: In this paper , the thermoelectric properties of molecular junctions incorporating multinuclear ruthenium alkynyl complexes with thioether anchors were investigated using the liquid metal technique.
Journal ArticleDOI
Tracking Energy Transfer across a Platinum Center
Tammy X. Leong,Brenna K. Collins,Sourajit Dey Baksi,Robert T. Mackin,Artem Sribnyi,Alexander L. Burin,John A. Gladysz,Igor V. Rubtsov +7 more
TL;DR: In this paper , the authors used relaxation-assisted two-dimensional infrared spectroscopy to track energy transfer across metal centers in platinum complexes featuring a triazole-terminated alkyne ligand of two or six carbons, a perfluorophenyl ligand, and two tri(p-tolyl)phosphine ligands.
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Acene Size‐Dependent Transition of The Radical Centers From the Metal to The Acene Parts In Monocationic Dinuclear (Diethynylacene)diyl Complexes
TL;DR: In this paper , the synthesis and results of electrochemical, spectroscopic, and theoretical studies of diruthenium (p−diethynylacene) diyl complexes, Me3Si(C≡C)2−Ru(dppe)2.
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A Metal Alkynyl Molecular Wire with PN ligands: Synthesis, Isomerization, Physical Properties and Single-Molecule Conductance
TL;DR: In this paper , a ruthenium trans-di(alkynyl) molecular wire 1H, trans-Ru(PN)2(C≡CC≡C-H)2, with the two mixed phosphine-pyridine supporting ligands (PN: 2-diphenylphosphinomethyl-6-methyl pyridine).
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Ru(0)-catalysed cross-dimerisation and -trimerisation of alkynyl- with butadienylheteroarenes.
TL;DR: In this paper , a series of di-and triheteroaryl compounds crosslinked by π-conjugated trienyl groups were studied using UV-visible absorption spectra, fluorescence emission spectra and TD-DFT calculations.
References
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Density-functional method for nonequilibrium electron transport
TL;DR: In this paper, an ab initio method for calculating the electronic structure, electronic transport, and forces acting on the atoms, for atomic scale systems connected to semi-infinite electrodes and with an applied voltage bias.
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Electronics using hybrid-molecular and mono-molecular devices
TL;DR: ‘mono-molecular’ electronics, in which a single molecule will integrate the elementary functions and interconnections required for computation, is proposed.
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Electron transport in molecular wire junctions.
TL;DR: Molecular conductance junctions are structures in which single molecules or small groups of molecules conduct electrical current between two electrodes and there is still limited correspondence between experimental and theoretical studies of these systems.
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Measurement of Single-Molecule Resistance by Repeated Formation of Molecular Junctions
Bingqian Xu,Nongjian Tao +1 more
TL;DR: The conductance of a single molecule connected to two gold electrodes was determined by repeatedly forming thousands of gold-molecule-gold junctions using conductance histograms, which revealed well-defined peaks at integer multiples of a fundamental conductance value.
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Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)
TL;DR: Since the late 1940s, the field of electron transfer processes has grown enormously, both in chemistry and biology as discussed by the authors, and the development of the field, experimentally and theoretically, as well as its relation to the study of other kinds of chemical reactions, presents an intriguing history, one in which many threads have been brought together.