Journal ArticleDOI
Catalytic chromium reduction using formic acid and metal nanoparticles immobilized in a metal-organic framework.
Mahendra Yadav,Qiang Xu +1 more
TLDR
The resulting composites were investigated in the reduction of Cr(VI) to Cr(III) using formic acid, showing that the Pt and Pd catalysts were active with the Pt nanoparticles immobilized in MOF exhibiting the best performance.About:
This article is published in Chemical Communications.The article was published on 2013-03-26. It has received 195 citations till now. The article focuses on the topics: Formic acid & Catalysis.read more
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Journal ArticleDOI
Metal–organic framework composites
Qi-Long Zhu,Qiang Xu +1 more
TL;DR: This review provides an overview of the significant advances in the development of diverse MOF composites reported till now with special emphases on the synergistic effects and applications of the composites.
Journal ArticleDOI
Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis
TL;DR: An overview of significant progress in the development of MNP/MOF composites, including various preparation strategies and characterization methods as well as catalytic applications is provided, with special emphasis on synergistic effects between the two components that result in an enhanced performance in heterogeneous catalysis.
Journal ArticleDOI
Photocatalytic Cr(VI) reduction in metal-organic frameworks: A mini-review
TL;DR: In this paper, a mini-review presented photocatalytic reduction of Cr(VI) into Cr(III) in some MOFs or their derivatives/composites.
Journal ArticleDOI
Application of metal and metal oxide nanoparticles@MOFs
Paolo Falcaro,Raffaele Ricco,Amirali Yazdi,Inhar Imaz,Shuhei Furukawa,Daniel Maspoch,Rob Ameloot,Jack D. Evans,Christian J. Doonan +8 more
TL;DR: Nanoparticles@MOFs composites combine the tailorable porosity of MOFs with the versatile functionality of metal or metaloxide nanoparticles as mentioned in this paper, and have been shown to possess unique functional properties.
Journal ArticleDOI
Highly dispersed palladium nanoparticles anchored on UiO-66(NH2) metal-organic framework as a reusable and dual functional visible-light-driven photocatalyst
TL;DR: This work represents the first example of using the MOFs-based materials as dual functional photocatalyst to remove different categories of pollutants simultaneously, and proves great potential for the design and application of MOFs -based materials.
References
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Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Hybrid porous solids: past, present, future
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.
Journal ArticleDOI
A chromium terephthalate-based solid with unusually large pore volumes and surface area.
Gérard Férey,Gérard Férey,Caroline Mellot-Draznieks,Christian Serre,Franck Millange,Julien Dutour,Suzy Surblé,Irene Margiolaki +7 more
TL;DR: This crystal structure for porous chromium terephthalate, MIL-101, with large poresizes and surface area has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.
Journal ArticleDOI
Ultrahigh Porosity in Metal-Organic Frameworks
Hiroyasu Furukawa,Nakeun Ko,Yong Bok Go,Naoki Aratani,Sang Beom Choi,Eunwoo Choi,A. Oezguer Yazaydin,Randall Q. Snurr,Michael O'Keeffe,Jaheon Kim,Omar M. Yaghi +10 more
TL;DR: The synthesis of a MOF in which zinc centers are bridged with long, highly conjugated organic linkers, but in which the overall symmetry of the networks created prevents formation of interpenetrating networks is described.
Journal ArticleDOI
The pervasive chemistry of metal–organic frameworks
Jeffrey R. Long,Omar M. Yaghi +1 more