Journal ArticleDOI
Catalytic effect of exfoliated zirconium phosphate on the curing behavior of benzoxazine
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TLDR
In this article, the effects of α-zirconium phosphate (i.e., α-ZrP) on the thermal curing of bisphenol A-based benzoxazine (Ba) was studied by preparing resin systems consisting of Ba and α ZrP.About:
This article is published in Thermochimica Acta.The article was published on 2017-04-10. It has received 35 citations till now. The article focuses on the topics: Curing (chemistry) & Differential scanning calorimetry.read more
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Zirconium phosphate (ZrP)-based functional materials: Synthesis, properties and applications
Huaping Xiao,Shuhai Liu +1 more
TL;DR: Zirconium phosphate (ZrP) and its organic derivative, Zrconium phosphonate, increasingly attract research interest due to their outstanding physical and chemical properties, both in their amorphous and in their crystalline phases as mentioned in this paper.
Journal ArticleDOI
Review on the Accelerated and Low-Temperature Polymerization of Benzoxazine Resins: Addition Polymerizable Sustainable Polymers.
Bimlesh Lochab,Monisha Monisha,Nagarjuna Amarnath,Pratibha Sharma,Sourav Mukherjee,Hatsuo Ishida +5 more
TL;DR: In this paper, the authors classified polybenzoxazine polymers based on their synthesis and evolution of structure, which led to classification of PBz in different generations, and discussed the role of additional functionalities in influencing the temperature of polymerization.
Journal ArticleDOI
Nanoreinforcements of Two-Dimensional Nanomaterials for Flame Retardant Polymeric Composites: An Overview
Shaolin Lu,Wei Hong,Xudong Chen +2 more
TL;DR: In this article, the current research status of two-dimensional nanomaterials as flame retardants is discussed, as well as a mechanism of how they can be applied for reducing the flammability of polymers.
Journal ArticleDOI
A high-performance functional phthalonitrile resin with a low melting point and a low dielectric constant
Minjie Wu,Jianjun Xu,Shengnan Bai,Xinggang Chen,Xiaoyan Yu,Kimiyoshi Naito,Zhenjiang Zhang,Qingxin Zhang +7 more
TL;DR: The prepared PBDP resin with outstanding thermal stability and low dielectric constant is an ideal candidate for aerospace industries, and microelectronic and other electronic packaging materials.
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Curing kinetics and thermal stability of novel siloxane-containing benzoxazines
TL;DR: In this article, a bis(p-aminophenoxy)diphenylsiloxane-based polybenzoxazine with an initial decomposition temperature of 420°C and a char yield of 74% was studied by in-situ Fourier Transform infrared spectroscopy.
References
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Journal ArticleDOI
ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data
Sergey Vyazovkin,Alan K. Burnham,José M. Criado,Luis A. Pérez-Maqueda,Crisan Popescu,Nicolas Sbirrazzuoli +5 more
TL;DR: In this article, the authors have developed recommendations for reliable evaluation of kinetic parameters (the activation energy, the preexponential factor, and the reaction model) from the data obtained by means of thermal analysis methods such as TGA, differential scanning calorimetry (DSC), and differential thermal analysis (DTA).
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The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods
TL;DR: In this article, a classification of model-free isoconversion methods for the calculation of activation energies of thermally activated reactions is proposed, by deriving expressions for the main sources of error which includes the inaccuracy in reaction rate measurement, approximations for the temperature integral and inaccuracies in determination of temperature for equivalent fraction transformed.
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Synthesis and Characterization of Novel Benzoxazine Monomers Containing Allyl Groups and Their High Performance Thermosets
Tarek Agag,Tsutomu Takeichi +1 more
TL;DR: In this paper, two novel benzoxazine monomers containing allyl groups, 3-allyl-3,4-dihydro-2H-1,3-benzoxazine and bis(3allyl, 3,4,dihd-ro- 2H 1,3)-isopropane, have been synthesized from phenol and Bisphenol A with allylamine and formaldehyde.
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A comparison of physical properties and fuel cell performance of Nafion and zirconium phosphate/Nafion composite membranes
Christopher Yang,Supramaniam Srinivasan,Andrew Bruce Bocarsly,S. Tulyani,Jay Burton Benziger +4 more
TL;DR: In this paper, the authors compared the physiochemical properties of Nafion 115 and a composite membrane of Zirconium phosphate (∼25 ¼wt.%) and found that the composite membrane has a greater rigidity that accounts for its improved fuel cell performance.