Journal ArticleDOI
Computational aspects of kinetic analysis: Part A: The ICTAC kinetics project-data, methods and results
Michael E. Brown,Marek Maciejewski,Sergey Vyazovkin,R. Nomen,J. Sempere,Alan K. Burnham,J. Opfermann,R. Strey,H. L. Anderson,A. Kemmler,R. Keuleers,J.F. Janssens,H.O. Desseyn,Chao-Rui Li,Tong B. Tang,B. Roduit,Jiří Málek,Takefumi Mitsuhashi +17 more
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TLDR
The results of the ICTAC Kinetics Project as mentioned in this paper have been used to forecast the tendencies for the future development of solid state kinetics, as well as the findings of the participants are compared.About:
This article is published in Thermochimica Acta.The article was published on 2000-07-31. It has received 794 citations till now.read more
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ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data
Sergey Vyazovkin,Alan K. Burnham,José M. Criado,Luis A. Pérez-Maqueda,Crisan Popescu,Nicolas Sbirrazzuoli +5 more
TL;DR: In this article, the authors have developed recommendations for reliable evaluation of kinetic parameters (the activation energy, the preexponential factor, and the reaction model) from the data obtained by means of thermal analysis methods such as TGA, differential scanning calorimetry (DSC), and differential thermal analysis (DTA).
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Biomass pyrolysis kinetics: A comparative critical review with relevant agricultural residue case studies
TL;DR: A critical review of kinetic models and mathematical approximations currently employed in solid state thermal analysis is provided and analysis of thermal decomposition data obtained from two agricultural residues, nutshells and sugarcane bagasse reveals the inherent difficulty and risks involved in modeling heterogeneous reaction systems.
Journal ArticleDOI
Isoconversional Kinetic Analysis of Thermally Stimulated Processes in Polymers
TL;DR: Isoconversional analysis of polymer kinetics has been studied extensively over the past decade as discussed by the authors and has been applied to a wide range of applications, including thermal degradation, crosslinking, glass transition, and glass and melt crystallization.
Journal ArticleDOI
Thermal decomposition kinetics of natural fibers: Activation energy with dynamic thermogravimetric analysis
TL;DR: In this article, a dynamic TG analysis under nitrogen was used to investigate the thermal decomposition processes of 10 types of natural fibers commonly used in the polymer composite industry, including wood, bamboo, agricultural residue, and bast fibers.
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Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction
TL;DR: In this paper, the authors review the pyrolysis of biomass constituents and possible secondary reactions and show that for most of the biomass species tested, the first order reaction rate constant is large and > 0.5 s−1.
References
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Kinetic Parameters from Thermogravimetric Data
A. W. Coats,J. P. Redfern +1 more
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
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A New Method of Analyzing Thermogravimetric Data
TL;DR: In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.
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Kinetic analysis of derivative curves in thermal analysis
TL;DR: In this article, two methods of obtaining kinetic parameters from derivative thermoanalytical curves are proposed based on the general form of kinetic formulae and are applicable to general types of reactions governed by a single activation energy.