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Journal ArticleDOI

Consecutive intramolecular hydroamination/asymmetric transfer hydrogenation under relay catalysis of an achiral gold complex/chiral Brønsted acid binary system.

TLDR
Consecutive hydroamination/asymmetric transfer hydrogenation under relay catalysis of an achiral gold complex/chiral Brønsted acid binary system has been described for the direct transformation of 2-(2-propynyl)aniline derivatives into tetrahydroquinolines with high enantiomeric purity.
Abstract
Consecutive hydroamination/asymmetric transfer hydrogenation under relay catalysis of an achiral gold complex/chiral Bronsted acid binary system has been described for the direct transformation of 2-(2-propynyl)aniline derivatives into tetrahydroquinolines with high enantiomeric purity.

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Synergistic catalysis: A powerful synthetic strategy for new reaction development

TL;DR: This perspective aims to highlight the benefits of synergistic catalysis using many of the successful examples of synergism catalysis found in the literature.
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Chiral Amine Synthesis – Recent Developments and Trends for Enamide Reduction, Reductive Amination, and Imine Reduction

TL;DR: The review examines the chiral amine literature from 2000-2009 concerning enantioselective and diastereoselectives methods for N-acylenamide and enamine reduction, reductive amination, and imine reduction.
References
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Journal ArticleDOI

Gold-Catalyzed Organic Reactions

TL;DR: Important vinylgold intermediates, the transmetalation from gold to other transition metals, the development of new ligands for gold catalysis, and significant contributions from computational chemistry are other crucial points for the field highlighted here.
Journal ArticleDOI

Gold-catalyzed organic transformations.

TL;DR: Thanks to gold-based catalysts, various organic transformations have been accessible under facile conditions with both high yields and chemoselectivity.
Journal ArticleDOI

Hydroamination: direct addition of amines to alkenes and alkynes.

TL;DR: Hydroamination of Alkenes and Alkynes under Microwave Irradiation and Nitromercuration Reactions 3878 9.8.4.5.
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