Controlling the Chromaticity of Small‐Molecule Light‐Emitting Electrochemical Cells Based on TIPS‐Pentacene

TLDR: In this paper, a photo-induced cycloaddition process of the 6,13-bis (triisopropylsilylethynyl) (TIPS)-pentacene is used to generate a high-energy emission.

Abstract: This work demonstrates a novel proof-of-concept to implement pentacene derivatives as emitters for the third generation of light-emitting electrochemical cells based on small-molecules (SM-LECs). Here, a straightforward procedure is shown to control the chromaticity of pentacene-based lighting devices by means of a photoinduced cycloaddition process of the 6,13-bis(triisopropylsilylethynyl) (TIPS)-pentacene that leads to the formation of anthracene-core dimeric species featuring a high-energy emission. Without using the procedure, SM-LECs featuring deep-red emission with Commission Internationale d'Eclairage (CIE) coordinates of x = 0.69/y = 0.31 and irradiance of 0.4 μW cm−2 are achieved. After a careful optimization of the cycloaddition process, warm white devices with CIE coordinates of x = 0.36/y = 0.38 and luminances of 10 cd m−2 are realized. Here, the mechanism of the device is explained as a host–guest system, in which the dimeric species acts as the high-energy band gap host and the low-energy bandgap TIPS-pentacene is the guest. To the best of the knowledge, this work shows the first warm white SM-LECs. Since this work is based on the archetypal TIPS-pentacene and the photoinduced cycloaddition process is well-knownfor any pentacenes, this proof-of-concept could open a new way to use these compounds for developing white lighting sources.