Journal ArticleDOI
Cross-coupling of aryltrimethylammonium iodides with arylzinc reagents catalyzed by amido pincer nickel complexes.
Xue-Qi Zhang,Zhong-Xia Wang +1 more
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TLDR
The cross-coupling reaction of aryltrimethylammonium iodides with aryal- or heteroarylzinc chlorides catalyzed by amido pincer nickel complexes was performed and requires low catalyst loading and displays broad substrate scope.Abstract:
The cross-coupling reaction of aryltrimethylammonium iodides with aryl- or heteroarylzinc chlorides catalyzed by amido pincer nickel complexes was performed. The reaction requires low catalyst loading and displays broad substrate scope.read more
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Transition-Metal-Catalyzed Cleavage of C-N Single Bonds.
TL;DR: This paper presents the results of aalysis experiments conducted at the BNLMS and Nankai University with real-time measurements of the response of the H2O-O2/O2 mixture to E2O/O3 mixture.
Journal ArticleDOI
Recent Developments in Negishi Cross-Coupling Reactions
TL;DR: In this paper, general methods for the preparation of polyfunctional zinc organometallics and their use in Negishi cross-coupling reactions are described, including new ligands and palladium catalysts.
Journal ArticleDOI
Nickel-Catalyzed Cross Couplings of Benzylic Ammonium Salts and Boronic Acids: Stereospecific Formation of Diarylethanes via C–N Bond Activation
TL;DR: A nickel-catalyzed cross coupling of benzylic ammonium triflates with aryl boronic acids to afford diarylmethanes and diarylethanes with excellent chirality transfer is developed, offering a new strategy for the synthesis of highly enantioenriched diarylehanes from readily available chiralbenzylic amines.
Journal ArticleDOI
Recent Advances in Catalysis with Transition‐Metal Pincer Compounds
TL;DR: In this article, the most recent relevant advances involving pincer complexes as catalysts are summarized, and a comprehensive overview of the most relevant advances in the field of catalysts is presented.
Journal ArticleDOI
Nickel-Catalyzed Reductive and Borylative Cleavage of Aromatic Carbon–Nitrogen Bonds in N-Aryl Amides and Carbamates
TL;DR: Mechanical studies revealed that nickel-catalyzed reaction of N-aryl amides with hydroborane or diboron reagents resulted in the formation of the corresponding reduction or borylation products, respectively.
References
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BookDOI
Metal-catalyzed cross-coupling reactions
TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.
Journal ArticleDOI
Aryl-aryl bond formation one century after the discovery of the Ullmann reaction.
Journal ArticleDOI
Palladium-Catalyzed Suzuki-Miyaura Cross-coupling Reactions Employing Dialkylbiaryl Phosphine Ligands
Ruben Martin,Stephen L. Buchwald +1 more
TL;DR: An overview of the use and impact of dialkylbiarylphosphine ligands in the Suzuki-Miyaura cross-coupling reaction and the utility of these ligands has been successfully demonstrated in a wide number of synthetic applications, including industrially relevant processes.
Journal ArticleDOI
Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners.
Journal ArticleDOI
Selected patented cross-coupling reaction technologies.
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