Journal ArticleDOI
Design, synthesis and reactivity with dichloro-bis(triphenylphosphine) platinum(II) of two triazenide compounds
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TLDR
In the presence of sodium nitrite, the reaction of methyl anthranilate and 2-aminopyridine or o-aminobenzoic acid gives two triazenes, 1]-(2-carboxymethyl)benzene]-3-[2-pyridine]triazene (HL) and 1-[(2carboxyethyl)-benzenes]-3]-o-amino acid]triaxene (H2L′), respectively, which have been characterized by X-ray crystallography, 31P NMR spectra,About:
This article is published in Inorganica Chimica Acta.The article was published on 2011-07-15. It has received 10 citations till now. The article focuses on the topics: Triazene & Triphenylphosphine.read more
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Properties and Promise of Catenated Nitrogen Systems As High-Energy-Density Materials
TL;DR: This review describes foundational subjects, methods, and metrics relevant to the energetic materials community and provides an overview of important classes of catenated nitrogen compounds ranging from theoretical investigation of hypothetical molecules to the practical application of real-world energetic materials.
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Aromatic fluoro-de-triazenation with boron trifluoride diethyl etherate under non-protic acid conditions
Mitja Kovac,Mitja Kovac,Marko Anderluh,Johnny Vercouillie,Denis Guilloteau,Patrick Emond,Sylvie Mavel +6 more
TL;DR: Fluoro-de-triazenation of 3,3-diethyl-1-aryltriazenes can be achieved by conventional or under microwave heating in carbon tetrachloride, in the presence of boron trifluoride diethyl etherate without any protic acid to avoid corresponding unwanted byproduct formation.
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Triazenide complexes of iridium. Evidence for [Ir(η1-N3Ph2)(HN3Ph2)(1,5-cod)], structures of [Ir2(μ-OMe)2(1,5-cod)2], [Ir2(μ-N3Ph2)2(1,5-cod)2], [Ir(η2-N3Ph2)(H)(SiPh3)(1,5-cod)], [Ir(η2-N3Ph2)(H)(SnPh3)(1,5-cod)] and [Ir(η2-N3Ph2)(SC6F5)2(1,5-cod)]
TL;DR: In this article, the reaction of [Ir2(μ-OMe)2(1,5-cod)2] with diphenyltriazene gives a product, formulated as [Ir(η1-N3Ph2)(HN3P2)(1, 5-cod)] on the basis of NMR data.
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pH-controlled synthesis of an aromatic triazene and its copper(II) complexation accompanied by an unexpected aromatic ring halogenation
TL;DR: In this article, an isomeric triazene (H2L) and an azo dye (D1) were synthesized from the reaction between 2-amino-3-cyano-4-chloro-5-formylthiophene and 2 amino-5nitrophenol under different pH values.
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Synthesis and spectroscopic studies of some new ortho functionalized triazene compounds and their reactivity with mercury (II) ion
TL;DR: In this paper, a series of triazene derivatives with a wide range of electronic characters were synthesized to understand the effect of the substituent identity in controlling the changes in their electronic absorption spectra and NMR chemical shifts, as well as their tendency for interaction with some heavy metals.
References
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The coordination chemistry of the amidine ligand
James Barker,Melvyn Kilner +1 more
TL;DR: In this article, a review of metal-metal bridging with the presence of the amidino group is presented, with a focus on bridging modes for the group and a reference to other aza-allyl systems.
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Triazenes: a versatile tool in organic synthesis.
TL;DR: This review highlights some of the recent advances and diversity possible with triazenes, a class of compounds which are stable and adaptable to numerous synthetic transformations.
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Triazenide complexes of the heavier alkaline earths: synthesis, characterization, and suitability for hydroamination catalysis.
Anthony G. M. Barrett,Mark R. Crimmin,Michael S. Hill,Peter B. Hitchcock,Gabriele Kociok-Köhn,Panayiotis Alexandrou Procopiou +5 more
TL;DR: A series of density-functional theory computational experiments have been undertaken to assist in the understanding of the triazenide ligand coordinates through both terminal and internal nitrogen centers in alkaline earths synthesized by either protonolysis or salt metathesis routes.