Drying of Granular Ceramic Films: I, Effect of Processing Variables on Cracking Behavior

TLDR: In this article, a critical cracking thickness (CCT) was determined, above which films would spontaneously crack during drying, and the effects of particle size, liquid surface tension, drying rate, dispersion stability, and sedimentation time were evaluated by a statistical design methodology.

Abstract: Drying of binder-free granular ceramic films was studied to identify processing variables which affect their cracking behavior. Films were prepared from electrostatically stabilized suspensions of α-alumina in water. A critical cracking thickness (CCT) was determined, above which films would spontaneously crack during drying. The effects of particle size, liquid surface tension, drying rate, dispersion stability, and sedimentation time were evaluated by a statistical design methodology. The CCT for films prepared on glass substrates was used as a measure of the effect of each variable on cracking. The statistically significant variables were particle size, dispersion stability, and sedimentation time. The effect of substrate constraint was also studied by producing films on a Teflon substrate and a pool of liquid Hg. The observations were consistent with a capillary formed tensile stress acting on the entire film rather than differential stress generated by a moisture gradient over the film thickness.