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Journal ArticleDOI

Effect of dissolved hydrogen on corrosion of Inconel Alloy 600 in high temperature hydrogenated water

TLDR
In this article, the effect of dissolved hydrogen (DH) levels on the Ni/NiO phase transition was investigated by employing electrochemical and exposure experiments, and the results showed that increasing DH in water decreased the thickness and the ionic defect transport resistance of the oxide film, in conjunction with the increase of Cr- but decrease of Ni-concentrations in the oxide.
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This article is published in Electrochimica Acta.The article was published on 2011-10-01. It has received 66 citations till now. The article focuses on the topics: Oxide & Corrosion.

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Effect of electropolishing on corrosion of nuclear grade 316L stainless steel in deaerated high temperature water

TL;DR: In this paper, the effect of change in surface composition and microstructure by electropolishing on corrosion of nuclear grade 316L stainless steel in deaerated high temperature water was investigated.
Journal ArticleDOI

Influence of dissolved oxygen concentration on the oxide film formed on Alloy 690 in high temperature water

TL;DR: In this paper, the properties of Alloy 690 oxide films under different dissolved oxygen (DO) concentrations in 290°C water were examined, and the results showed that the oxide films formed under low DO became much thicker when immersed under high DO, with gradual development of spinel particles and NiO base layer.
Journal ArticleDOI

Effects of boundary migration and pinning particles on intergranular oxidation revealed by 2D and 3D analytical electron microscopy

TL;DR: In this paper, Alloy 600 samples in the thermally treated (TT) and solution-annealed (SA) conditions were analyzed after exposure to 480°C hydrogenated steam, and 3D serial sectioning of the boundaries revealed strong variations in the intergranular oxide for 600TT, particularly in the depth of oxide penetration.
Journal ArticleDOI

Environmentally assisted crack growth in one-dimensionally cold worked Alloy 690TT in primary water

TL;DR: In this paper, the authors investigated the effect of hydrogen on crack growth in Alloy 690 cold and found that hydrogen could promote SCC growth when increasing dissolved hydrogen from a very low level.
Journal ArticleDOI

The effects of dissolved hydrogen on the corrosion behavior of Alloy 182 in simulated primary water

TL;DR: In this paper, the effects of dissolved hydrogen (DH) on the corrosion behavior of Alloy 182 in high temperature (320 °C) water were studied using in situ electrochemical measurements and ex situ surface analyses.
References
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Book

Electrochemical Impedance Spectroscopy

TL;DR: In this paper, the authors provide guidelines for experimental design, discuss the relevance of accuracy contour plots to wiring and instrumentation selection, and emphasize the importance of the Kramers-Kronig relations to data validation and analysis.
Journal ArticleDOI

A Point Defect Model for Anodic Passive Films I . Film Growth Kinetics

TL;DR: In this paper, a model based on the movement of point defects in an electrostatic field is proposed to interpret the growth behavior of a passive film on a metal surface, which results in a logarithmic growth law.
Journal ArticleDOI

Corrosion in high-temperature and supercritical water and aqueous solutions: a review

TL;DR: In this paper, the authors review some of the common corrosion phenomena and describe the predominant corrosion mechanisms in high-temperature and supercritical water, including intergranular corrosion, pitting, general corrosion, and stress corrosion cracking.
Journal ArticleDOI

Electrolytic Dissolution of Binary Alloys Containing a Noble Metal

TL;DR: In this paper, the ionization and redeposition of binary alloys, coupling of the anodic reactions in accordance with the concepts of irreversible thermodynamics, and volume diffusion in the presence of given supersaturations of single and double vacancies are analyzed theoretically.
Journal ArticleDOI

The mechanism of high temperature aqueous corrosion of stainless steels

John Robertson
- 01 Jan 1991 - 
TL;DR: In this article, it was shown that the corrosion rate of stainless steels in high temperature, deoxygenated water is controlled by the solid state diffusion of Fe ions along grain boundaries in the oxide layer.
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