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Effect of fiber treatments on tensile and thermal properties of starch/ethylene vinyl alcohol copolymers/coir biocomposites.

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TLDR
Coir fibers received three treatments, namely washing with water, alkali treatment (mercerization) and bleaching, which produced surface modifications and improved the thermal stability of the fibers and consequently of the composites.
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This article is published in Bioresource Technology.The article was published on 2009-11-01 and is currently open access. It has received 277 citations till now. The article focuses on the topics: Natural fiber & Fiber.

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Biocomposites reinforced with natural fibers: 2000–2010

TL;DR: A comprehensive review of literature on bio-fiber reinforced composites is presented in this paper, where the overall characteristics of reinforcing fibers used in biocomposites, including source, type, structure, composition, as well as mechanical properties, are reviewed.
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Cellulose nanowhiskers from coconut husk fibers: Effect of preparation conditions on their thermal and morphological behavior

TL;DR: In this paper, the effects of preparation conditions on the thermal and morphological behavior of the nanocrystals were investigated and a possible correlation between preparation conditions and particle size was not observed.
Journal ArticleDOI

In State of Art: Mechanical and tribological behaviour of polymeric composites based on natural fibres

TL;DR: In this paper, a comprehensive literature review on the mechanical and tribological behavior of polymeric composites based on natural fibres is introduced, where the effects of volume fraction, orientations, treatments, and physical characteristics of different types of natural fibers on the properties of several thermoset and thermoplastic polymers are addressed.
Journal ArticleDOI

Natural Fiber Reinforced Composites

TL;DR: In this paper, the use of bio-based fibers as composite reinforcement has been addressed and the influence of textile operations on creating various fiber architectures with resulting reinforcing capabilities, along with the methods in which natural fiber reinforced composites can be processed.
Journal ArticleDOI

Effect of fiber surface treatments on mechanical and abrasive wear performance of polylactide/jute composites

TL;DR: In this article, the surface modified fibers were characterized by FTIR spectroscopy and the degree of interfacial adhesion between the jute fiber and PLA was estimated using adhesion parameter obtained through DMA data.
References
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Journal ArticleDOI

Surface modifications of natural fibers and performance of the resulting biocomposites: An overview

TL;DR: A review of biocomposites highlighting recent studies and developments in natural fibers, bio-polymers, and various surface modifications of natural fibers to improve fiber-matrix adhesion is presented in this paper.
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Natural, Fibers, Biopolymers and Biocomposites

TL;DR: A.K. Mohanty, M. Misra, L.T. Drzal, and R. Narayan as discussed by the authors discussed the potential of natural fiber composites in automotive applications.
Journal ArticleDOI

Wood-plastic composites as promising green-composites for automotive industries!

TL;DR: From a technical point of view, these bio-based composites will enhance mechanical strength and acoustic performance, reduce material weight and fuel consumption, lower production cost, improve passenger safety and shatterproof performance under extreme temperature changes, and improve biodegradability for the auto interior parts.
Journal ArticleDOI

Effect of fiber surface treatment on the fiber-matrix bond strength of natural fiber reinforced composites

TL;DR: In this paper, an alkaline treatment was used to enhance both the matrix fiber wetting and the chemical surface modification in order to improve the physicochemical interactions at the fiber-matrix interphase.
Journal ArticleDOI

Effect of chemical treatment on the tensile properties of short sisal fibre-reinforced polyethylene composites

TL;DR: The effect of chemical treatment on the tensile properties of sisal fiber-reinforced LDPE composites was investigated in this article, where various chemical treatments were carried out to improve the bonding at the fibre polymer interface.
Related Papers (5)
Frequently Asked Questions (19)
Q1. What contributions have the authors mentioned in the paper "Effect of fiber treatments on tensile and thermal properties of starch/ethylene vinyl alcohol copolymers/coir biocomposites" ?

In this paper, S.H. Imam et al. evaluated the mechanical and thermal properties of starch/poly ( ethylene vinyl alcohol ) copolymer ( EVOH ) blends with Coir fibers. 

Bleaching with hydrogen peroxide isanother chemical treatment widely used in the textile industry that provides surface modification of the fibers (Rout et al., 2001; Salam, 2006). 

The wetting produced a stronger bond at the interface and reduced the available surface area for moisture desorption, resulting in a delay in moisture evaporation. 

3. Changes occurring in the fibers due to the treatments led to a positive effect on the thermal degradation behavior of the composites, as indicated by the higher thermal stability of the treated composites. 

The alkali treatment changed the color of the fibers from brown to dark brown and the bleaching with H2O2 produced yellowish brown fibers, indicating that the expected modification (removal of wax, fatty substances and lignin) might have been achieved, as demonstrated in works of other research groups (Katz, 1977; Rout et al., 2001). 

due to starch’s excessive hydrophilicity and brittleness, blending starch with conventional polymers is a promising approach to improve its drawbacks (Medeiros et al., 2008). 

According to these authors, the tendency to release moisture at a higher temperature in the treated composites could be due to the improved wetting of the finely separated fibers by the matrix. 

Coconut fibers (200 g) were added to a 2 L solution containing 320 mL (30%; w/w) hydrogen peroxide and 1 g sodium hydroxide at 85 C and stirred for 1 h. 

All specimens were coated with Gold–Palladium for 45 s in a Denton Desk II sputter coating unit (Denton Vacuum USA, Moorestown, NJ). 

All the treatments removed surface impurities on fibers, producing modifications on the surface and improving thermal stability of both fibers and fiber-reinforced composites. 

as reported by Mohanty et al. (2001), alkali treatment reduces fiber diameter and thereby increases the aspect ratio, improving mechanical characteristics of the composites. 

Prasad et al. (1983) studying composites made of polyester resin and coir fibers, obtained a 15% increase in tensile strength when fibers were soaked in a 5% NaOH aqueous solution at 28 C for 72–76 h. 

derivate from variety of botanical sources (cereals, legumes, and tubers), is widely available raw material for use in bioplastics (Bastioli et al., 1995; Kumar and Singh, 2008). 

As shown in Table 1, the elongation at break (e) of the starch/ EVOH blends decreased and tensile modulus (E) increased considerably by approximately 74% with the incorporation of fibers, due to the rigid nature of the fibers reducing the ductile behavior of the composites. 

According to Varma et al. (1986), upon alkali treatment, there was a partial loss of cementing material via the rupture of ester linkages between polyuronic acid and lignin, increasing the percentage of crystallinity index of alkali-treated fibers. 

The hemicellulose degradation temperature increased slightly with treatment from 314 C for untreated fiber-composite to 318, 317, 317, and 315 C for washed, mercerized and blenched fiber-reinforced composites, respectively. 

One of most used modifications is the treatment with an alkali solution (Corradini et al., 2006; Prasad et al., 1983; Ray et al., 2001). 

Interfacial adhesion between coir and natural rubber was increased by treatment of the coir fibers with alkali (Geethamma, 1998). 

some authors (Sreenivasan et al., 1996; Varma et al., 1986) reported that coir fibers changed their crystallinity through alkali treatment.